The Basics of Spectroscopy

by
Format: Paperback
Pub. Date: 2001-06-01
Publisher(s): Society of Photo Optical
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Summary

Spectroscopy--the study of matter using electromagnetic radiation--and its applications as a scientific tool are the focus of this tutorial. Topics covered include the interaction of light with matter, spectrometer fundamentals, quantum mechanics, selection rules, and experimental factors.

Table of Contents

Preface xi
A Short History
3(16)
Introduction
3(1)
Matter
3(5)
Light
8(5)
Quantum mechanics and spectroscopy
13(6)
References
17(2)
Light and Its Interactions
19(14)
Properties of light waves
19(3)
Interactions of light with matter
22(7)
Reflection
22(2)
Transmission
24(2)
Absorption
26(2)
Polarization
28(1)
Transparent media for different spectral regions
29(4)
References
31(2)
Spectrometers
33(20)
Introduction
33(1)
Emission and absorption spectrometers
33(2)
Fourier transform spectrometers
35(5)
Magnetic resonance spectrometers
40(5)
Fourier transform NMR
45(8)
References
51(2)
The Spectrum
53(12)
Introduction
53(1)
Types of spectroscopy
53(3)
Units of the y axis
56(4)
Units of the x axis
60(3)
Typical examples
63(2)
References
64(1)
The Shapes of Spectral Signals
65(10)
Introduction
65(1)
The heights of lines
65(2)
Beer's (?) law
67(2)
The widths of lines
69(6)
References
73(2)
Quantum Mechanics and Spectroscopy
75(16)
Introduction
75(1)
The need for quantum mechanics
75(3)
Planck's theory and Einstein's application
78(2)
Bohr's model
80(2)
Quantum mechanics
82(5)
Perturbation theory
87(1)
Application to spectroscopy
88(3)
References
90(1)
Selection Rules
91(14)
Introduction
91(1)
``Dipole moment'' selection rules
91(5)
Symmetry arguments for M
96(2)
Summary of selection rules
98(7)
Electronic spectroscopy
99(2)
Pure rotational and vibrational spectroscopy
101(1)
Magnetic resonance spectroscopy
102(1)
Violations, mixing types of motions
103(1)
References
104(1)
Resolution and Noise
105(14)
Introduction
105(1)
Resolution in dispersive spectrometers
105(3)
Resolution in Fourier transform spectrometers
108(4)
Noise: sources
112(2)
Noise: minimizing
114(5)
References
118(1)
Index 119

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