
Ceramic Processing and Sintering
by Rahaman; Mohamed N.-
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Summary
Author Biography
Table of Contents
Preface to the Second Edition | p. v |
Preface to the First Edition | p. vii |
Ceramic Fabrication Processes: An Introductory Overview | p. 1 |
Introduction | p. 1 |
Ceramic Fabrication Processes | p. 3 |
Production of Polycrystalline Ceramics from Powders: An Overview | p. 28 |
A Case Study in Processing: The Fabrication of TiO[subscript 2] from Powders | p. 41 |
Concluding Remarks | p. 43 |
Problems | p. 44 |
References | p. 45 |
Synthesis of Powders | p. 49 |
Introduction | p. 49 |
Desirable Powder Characteristics | p. 49 |
Powder Synthesis Methods | p. 51 |
Powder Preparation by Mechanical Methods | p. 52 |
Powder Synthesis by Chemical Methods | p. 62 |
Concluding Remarks | p. 118 |
Problems | p. 118 |
References | p. 120 |
Powder Characterization | p. 125 |
Introduction | p. 125 |
Physical Characterization | p. 126 |
Chemical Composition | p. 156 |
Crystal Structure and Phase Composition | p. 162 |
Surface Characterization | p. 164 |
Concluding Remarks | p. 176 |
Problems | p. 177 |
References | p. 179 |
Science of Colloidal Processing | p. 181 |
Introduction | p. 181 |
Types of Colloids | p. 183 |
Attractive Surface Forces | p. 183 |
Stabilization of Colloidal Suspensions | p. 190 |
Electrostatic Stabilization | p. 191 |
Steric Stabilization | p. 211 |
Electrosteric Stabilization | p. 222 |
Structure of Consolidated Colloids | p. 227 |
Rheology of Colloidal Suspensions | p. 230 |
Concluding Remarks | p. 242 |
Problems | p. 243 |
References | p. 245 |
Sol-Gel Processing | p. 248 |
Introduction | p. 248 |
Types of Gels | p. 250 |
Sol-Gel Processing of Aqueous Silicates | p. 254 |
Metal Alkoxides | p. 260 |
Sol-Gel Processing of Silicon Alkoxides | p. 266 |
Sol-Gel Preparation Techniques | p. 305 |
Applications of Sol-Gel Processing | p. 315 |
Concluding Remarks | p. 323 |
Problems | p. 323 |
References | p. 324 |
Powder Consolidation and Forming of Ceramics | p. 328 |
Introduction | p. 328 |
Packing of Particles | p. 330 |
Additives and Ceramic Forming | p. 344 |
Forming of Ceramics | p. 360 |
Drying of Granular Ceramics | p. 405 |
Binder Removal | p. 409 |
Green Microstructures and Their Characterization | p. 418 |
Concluding Remarks | p. 418 |
Problems | p. 419 |
References | p. 421 |
Sintering of Ceramics: Fundamentals | p. 425 |
Introduction | p. 425 |
Driving Force for Sintering | p. 427 |
Defects in Crystalline Solids | p. 428 |
Diffusion in Crystalline Solids | p. 441 |
Chemical Potential | p. 451 |
Diffusional Flux Equations | p. 459 |
Vapor Pressure Over a Curved Surface | p. 461 |
Diffusion in Ionic Crystals: Ambipolar Diffusion | p. 462 |
Concluding Remarks | p. 466 |
Problems | p. 467 |
References | p. 468 |
Theory of Solid-State and Viscous Sintering | p. 470 |
Introduction | p. 470 |
Mechanisms of Sintering | p. 471 |
Effects of Grain Boundaries | p. 473 |
Theoretical Analysis of Sintering | p. 476 |
Scaling Laws | p. 477 |
Analytical Models | p. 482 |
Numerical Simulation of Sintering | p. 506 |
Phenomenological Sintering Equations | p. 510 |
Sintering Diagrams | p. 511 |
Sintering with an Externally Applied Pressure | p. 514 |
The Stress Intensification Factor | p. 522 |
The Sintering Stress | p. 524 |
Measurement of the Sintering Stress and Stress Intensification Factor | p. 527 |
Alternative Derivation of the Sintering Equations | p. 530 |
Concluding Remarks | p. 535 |
Problems | p. 536 |
References | p. 537 |
Grain Growth and Microstructure Control | p. 540 |
Introduction | p. 540 |
General Features of Grain Growth | p. 541 |
Ostwald Ripening: The LSW Theory | p. 546 |
Topological and Interfacial Tension Requirements | p. 554 |
Normal Grain Growth in Dense Solids | p. 556 |
Abnormal Grain Growth in Dense Solids | p. 567 |
Mechanisms Controlling the Boundary Mobility | p. 573 |
Grain Growth and Pore Evaluation in Porous Solids | p. 585 |
Simultaneous Densification and Grain Growth | p. 602 |
Fabrication Principles for Ceramics with Controlled Microstructure | p. 611 |
Concluding Remarks | p. 614 |
Problems | p. 615 |
References | p. 616 |
Liquid-Phase Sintering | p. 620 |
Introduction | p. 620 |
Elementary Features of Liquid-Phase Sintering | p. 622 |
Stages of Liquid-Phase Sintering | p. 624 |
Thermodynamic and Kinetic Factors | p. 627 |
Grain Boundary Films | p. 639 |
The Basic Mechanisms of Liquid-Phase Sintering | p. 646 |
Hot Pressing with a Liquid Phase | p. 670 |
Use of Phase Diagrams in Liquid-Phase Sintering | p. 671 |
Activated Sintering | p. 677 |
Vitrification | p. 678 |
Concluding Remarks | p. 682 |
Problems | p. 684 |
References | p. 685 |
Special Topics in Sintering | p. 688 |
Introduction | p. 688 |
Rayleigh Instability and Microstructural Evolution | p. 689 |
Inhomogeneities and Their Effects on Sintering | p. 693 |
Constrained Sintering I: Rigid Inclusions | p. 702 |
Constrained Sintering II: Adherent Thin Films and Multilayers | p. 723 |
Thin Films: Grain Growth and Dimensional Stability | p. 733 |
Solid Solution Additives and the Sintering of Ceramics | p. 739 |
Sintering with Chemical Reaction: Reaction Sintering | p. 754 |
Viscous Sintering with Crystallization | p. 763 |
Concluding Remarks | p. 773 |
Problems | p. 774 |
References | p. 775 |
Densification Process Variables and Densification Practice | p. 779 |
Introduction | p. 779 |
Conventional Sintering | p. 780 |
Microwave Sintering | p. 818 |
Pressure Sintering | p. 829 |
Concluding Remarks | p. 841 |
Problems | p. 841 |
References | p. 843 |
Physical Constants | p. 847 |
SI Units--Names and Symbols | p. 849 |
Conversion of Units and Decimal Fractions and Multiples | p. 851 |
Ionic Crystal Radii (in units of 10[superscript -10] m) | p. 853 |
Density and Melting Point of Some Elements, Ceramics, and Minerals | p. 855 |
Aperture Size of U.S. Standard Wire Mesh Sieves (ASTM E 11:87) | p. 859 |
Index | p. 861 |
Table of Contents provided by Ingram. All Rights Reserved. |
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