Handbook of Fuel Cells Advances in Electrocatalysis, Materials, Diagnostics and Durability, Volumes 5 and 6

by ; ;
Edition: 1st
Format: Hardcover
Pub. Date: 2009-04-20
Publisher(s): Wiley
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Summary

A valuable addition to the established and highly acclaimed Handbook of Fuel Cells (2003). Highlights recent developments, particularly in the fields of new materials, molecular modelling and durability. Covers key topics and concepts essential to the development of reliable and cost-effective commercial fuel cells.

Author Biography

Wolf Vielstich started research work on Fuel Fells and Fischer-Tropsch Synthesis at Ruhrchemie / Oberhausen. Working in the field of Fundamental and Applied Electrochemistry at the Institute of Physical Chemistry of Bonn University, he completed his Habilitation in Physical Chemistry in 1962. From 1965 he was a professor and director at the Bonn Institute. His special interest was new experimental methods like Rotating Ring Electrodes, online MS, Insitu IR and UHV-analysis of electrode surfaces, as well as to Batteries and Fuel Cells. His work in Electrochemistry has resulted in more than 250 publications, over 10 patents, books on Fuel Cells and Electrochemical Kinetics, and textbooks on Electrochemistry. From 1986 to 1993, Professor Vielstich was co-ordinator of the first European project on the DMFC and in 1998 he received the Faraday Medal of the Royal Chemical Society, UK.

Hubert A. Gasteiger has spent 9 years in academic research in fundamental electrocatalysis and fuel cell-related gas-phase catalysis, plus 5 years of industrial research and development in fuel cell components development. Dr Gasteiger was involved in the stack and stack-component design for GM / Opel's H2-powered Fuel Cell Cars (H1, H2, and H3), and since 1998 has been manager in stack components (membranes, catalysts, bipolar plate materials and coatings, MEAs) development at GM/Opel's Global Alternative Propulsion Center in Mainz-Kastel, Germany, and at GM's Fuel Cell Activities facility in Honeoye Falls, New York, USA. Dr Gasteiger has published 45 publications in refereed journals and co-chaired the 2000 Gordon Research Conference on Fuel Cells.

Harumi Yokokawa

1972 - Graduated from Nuclear Engineering department, University of Tokyo
1977 - Graduated from Doctor course of University of Tokyo
Title of Doctoral work "Calorimetric Investigation of Uranium Compounds"
1977 - Join to National Chemical Laboratory for Industry, Agency for Industrial Science and Technology, Ministry of International Trade and Industry (MITI)
1978–1980 - Research Associated in James Franck Institute, University of Chicago
1982 - Senior researcher, National Chemical Laboratory for Industry
1993 - National Institute of Materials and Chemical Research, AIST, MITI
2001 - National Institute of Advanced Industrial Science and Technology

Awards

1989 - Award by Japan Information Center for Science and Technology on "Construction of Thermodynamic database and its advanced utilization"
2001 - Award by Minister of Science and Technology Agency on "Construction of Thermodynamic database and its applications to energy related materials."
2002 - Outstanding Achievement Awards from the High Temperature Materials Divsion, The Electrochemical Society, Inc., "In recognition of his contributions to the practical applications of thermochemistry to high temperature materials research and technology, especially in the area of solid oxide fuel cells."

Table of Contents

Contributors to Volume 5 and 6
Foreword
Preface
Abbreviations and Acronyms
Electrocatalyst Materials For Low Temperature Fuel Cells
Novel Catalysts
Platinum monolayer oxygen reduction electrocatalysts
Oxygen reduction on platinum bimetallic alloy catalysts
Dealloyed Pt bimetallic electrocatalysts for oxygen reduction
Transition metal/polymer catalysts for O2 reduction
Time to move beyond transition metal-N-C catalysts for oxygen reduction
Catalysts for the electro-oxidation of small molecules
Influence of size on the electrocatalytic activities of supported metal nanoparticles in fuel cell-related reactions
Enzyme catalysis in biological fuel cells
Fundamental Catalysis Models
Density functional theory applied to electrocatalysis
First-principles modeling for the electrooxidation of small molecules
On the pathways of methanol and ethanol oxidation
Reaction pathway analysis and reaction intermediate detection
via simultaneous differential electrochemical mass spectrometry
(DEMS) and attenuated total reflection fourier transform infrared spectroscopy (ATR-FTIRS)
Methanol oxidation on oxidized Pt surface
Mechanistic aspects of carbon monoxide oxidation
Catalyst Durability
Platinum dissolution models and voltage cycling effects: platinum dissolution in polymer electrolyte fuel cell (PEFC) and low-temperature fuel cells
Catalyst and catalyst-support durability
Effects of contaminants on catalyst activity
Conductive Membranes For Lowtemperature Fuel Cells
Novel Materials
Design rules for the improvement of the performance of hydrocarbon-based membranes for proton exchange membrane fuel cells (PEMFC)
High-temperature polybenzimidazole-based membranes
Radiation-grafted proton conducting membranes
Alkaline anion-exchange membranes for low-temperature fuel cell application
Characterization
Colloidal structure of ionomer solutions
Conductivity, permeability, and ohmic shorting of ionomeric membranes
Membrane Durability
Highly durable PFSA membranes
Factors influencing ionomer degradation
Chemical and mechanical membrane degradation
Mechanical durability characterization and modeling of ionomeric membranes
Materials For High Temperature Fuel Cells
Fundamental Models
Mechanistic understanding and electrochemical modeling of mixed conducting (SOFC) electrodes
Elementary kinetic modeling of solid oxide fuel cell electrode reactions
Mechanical stability
Novel Materials
Factors limiting the low-temperature operation of SOFCs
New oxide cathodes and anodes
New high-temperature proton conductors for fuel cells and gas separation membranes
Nanoimpact on electrode and electrolyte layers with Micro-Electro-Mechanical System (MEMS) technique
Materials Durability
Durability of metallic interconnects and protective coatings
Impact of impurities and interface reaction on electrochemical activity
Application of secondary ion mass spectrometry (SIMS) technique on the durability of solid oxide fuel cell (SOFC) materials
Durability of cathodes including Cr poisoning
Durable sealing concepts with glass sealants or compression seals
Advanced Diagnostics, Models, & Design
Low-Temperature Fuel Cells
Direct three-dimensional visualization and morphological analysis of Pt particles supported on carbon by transmission electron microtomography
Design approaches for determining local current and membrane resistance in polymer electrolyte fuel cells (PEFCs)
Heat and water transport models for polymer electrolyte fuel cells
Proton exchange membrane fuel cell (PEMFC) down-the-channel performance model
Use of neutron imaging for proton exchange membrane fuel cell (PEMFC) performance analysis and design
Local transient techniques in polymer electrolyte fuel cell (PEFC) diagnostics
Proton exchange membrane fuel cell (PEMFC) flow-field design for improved water management
Performance during start-up of proton exchange membrane (PEM) fuel cells at subfreezing conditions
Performance impact of cationic contaminants
Modeling the impact of cation contamination in a polymer electrolyte membrane fuel cell
Performance modeling and cell design for high concentration methanol fuel cells
Design concepts and durability challenges for mini fuel cells
High-Temperature Fuel Cells
New diagnostic methods for the polarized state
Electrochemical impedance spectroscopy as diagnostic tool
Observation and modeling of thermal stresses in cells and cell stacks
Performance Degradation
Low-Temperature Fuel Cells
Carbon-support corrosion mechanisms and models
Electrode degradation mechanisms studies by current distribution measurements
Electron microscopy to study membrane electrode assembly (MEA) materials and structure degradation
Proton exchange membrane fuel cell degradation: mechanisms and recent progress
Cold-start durability of membrane-electrode assemblies
Field experience with fuel cell vehicles
Membrane and catalyst performance targets for automotive fuel cells
Field experience with portable DMFC products
High-Temperature Fuel Cells
Overview of solid oxide fuel cell degradation
Methane reforming kinetics, carbon deposition, and redox durability of Ni/8 yttria-stabilized zirconia (YSZ) anodes
Sulfur poisoning on Ni catalyst and anodes
Ni shorting in relation to acid-base equilibrium of molten carbonate for molten cabonate fuel cell (MCFC) application
Impact of impurities on reliability of materials in solid oxide fuel cell (SOFC) stack/modules
Field experience with molten carbonate fuel cells (MCFCs) and solid oxide fuel cells (SOFCs) with an emphasis on degradation
Subject Index
Table of Contents provided by Publisher. All Rights Reserved.

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