Basic Inorganic Chemistry

by ; ;
Edition: 3rd
Format: Hardcover
Pub. Date: 1995-01-18
Publisher(s): Wiley
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Summary

Explains the basics of inorganic chemistry with a primary emphasis on facts; then uses the student's growing factual knowledge as a foundation for discussing the important principles of periodicity in structure, bonding and reactivity. New to this updated edition: improved treatment of atomic orbitals and properties such as electronegativity, novel approaches to the depiction of ionic structures, nomenclature for transition metal compounds, quantitative approaches to acid-base chemistry, Wade's rules for boranes and carboranes, the chemistry of major new classes of substances including fullerenes and silenes plus a chapter on the inorganic solid state.

Author Biography

F. ALBERT COTTON, PhD, is a professor in the Department of Chemistry at Texas A&M University.

SIR GEOFFREY WILKINSON, PhD, was a professor in the Department of Chemistry at the Imperial College of Science, Technology, and Medicine in London, United Kingdom.

Table of Contents

Part 1 First Principles 1(270)
Some Preliminaries
3(32)
The Electronic Structure of Atoms
35(38)
Structure and Bonding in Molecules
73(52)
Ionic Solids
125(22)
The Chemistry of Selected Anions
147(18)
Coordination Chemistry
165(54)
Solvents, Solutions, Acids, and Bases
219(22)
The Periodic Table and the Chemistry of the Elements
241(30)
Part 2 The Main Group Elements 271(230)
Hydrogen
273(14)
The Group IA(1) Elements: Lithium, Sodium, Potassium, Rubidium, and Cesium
287(20)
The Group IIA(2) Elements: Beryllium, Magnesium, Calcium, Strontium, and Barium
307(12)
Boron
319(38)
The Group IIIB(13) Elements: Aluminum, Gallium, Indium, and Thallium
357(12)
Carbon
369(14)
The Group IVB(14) Elements: Silicon, Germanium, Tin, and Lead
383(16)
Nitrogen
399(18)
The Group VB(15) Elements: Phosphorus, Arsenic, Antimony, and Bismuth
417(18)
Oxygen
435(16)
The Group VIB(16) Elements: Sulfur, Selenium, Tellurium, and Polonium
451(14)
The Halogens: Fluorine, Chlorine, Bromine, Iodine, and Astatine
465(18)
The Noble Gases
483(8)
Zinc, Cadmium, and Mercury
491(10)
Part 3 Transition Elements 501(138)
Introduction to the Transition Elements: Ligand Field Theory
503(42)
The Elements of the First Transition Series
545(42)
The Elements of the Second and Third Transition Series
587(28)
Scandium, Yttrium, Lanthanum, and the Lanthanides
615(10)
The Actinide Elements
625(14)
Part 4 Some Special Topics 639(146)
Metal Carbonyls and Other Transition Metal Complexes with πAcceptor (π-Acid) Ligands
641(26)
Organometallic Compounds
667(36)
Stoichiometric and Catalytic Reactions of Organometallic Compounds
703(26)
Bioinorganic Chemistry
729(28)
The Inorganic Solid State
757(28)
Appendix I Aspects of Symmetry and Point Groups 785(26)
Appendix IIA Table of the Hydrogen-Like Atomic Orbital Wave Functions 811(2)
Appendix IIB Ionization Enthalpies of the Elements 813(2)
Appendix IIC Ionic Radii 815(4)
Appendix IID Electron Attachment Enthalpies of Selected Elements 819(2)
Appendix IIE A Comparison of Electronegativity Values (Pauling Units) from Four Sources 821(2)
Glossary 823(10)
Index 833

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