Biomolecular Catalysis Nanoscale Science and Technology

by ; ;
Edition: 1st
Format: Hardcover
Pub. Date: 2008-06-23
Publisher(s): American Chemical Society
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Summary

This symposium series volume provides up-to-date reviews on synthesis, characterization, and applications of nanostructured systems in biocatalytic processes. The first part of the book describes the use of various nanostructures, including nanoporous materials, nanotubes, nanofibers and nanoparticles, and composite materials for biocatalysis. These chapters demonstrate the current frontier exploration and the most popular structures for nanobiocatalysis. The second part of the book illustrates potential applications of nanoscale biocatalysts in heterogeneous catalysis, biosensors, energy conversion, reaction engineering, and nano-transport. Nanostructured materials are currently a hot research topic with many academic, industrial, and government laboratories doing basic and applied R&D. Amalgamating these materials and biomolecular catalysts provide unprecedented capabilities in developing new functional materials that can be utilized in heterogeneous catalytic reactions, biodetection, energy harvesting, drug synthesis and delivery.

Author Biography


Dr. Jungbae Kim received his B.S. and M.S. degrees in Chemical Engineering from Seoul National University, Korea, in 1986 and 1988, and Ph.D. degree in Biochemical Engineering from University of Iowa in 1995. He is currently a Senior Research Scientist at the Pacific Northwest National Laboratory.
Dr. Seong H. Kim received his B.S. and M.S. degrees in Chemistry from Yonsei University, Korea, in 1990 and 1992 and his Ph.D. degree in Chemistry from Northwestern University in 1998. After doing postdoctoral research at University of California at Berkeley, he moved to the Department of Chemical Engineering, the Pennsylvania State University in 2001.
Dr. Ping Wang received his B.S. degree in 1985, M. S. degree in chemical engineering from East China University of Science and Technology (Shanghai), and Ph.D. degree in 1995 in chemical engineering from Tufts University. He is currently an Associate Professor of Bioproducts and Biosystems Engineering at University of Minnesota.

Table of Contents

Nanostructures for Biomolecular Catalysis
Nanoporous Materials
General Synthesis of Ordered Nonsiliceous Mesoporous Materialsp. 2
Proteins in Mesoporous Silicatesp. 49
Enzyme Stabilization Involving Molecular Evolution and Immobilization in Mesoporous Materialsp. 61
Microperoxidase-ll Immobilized in a Metal Organic Frameworkp. 76
Nanotubes, Nanofibers, and Nanoparticles
Protein-Carbon Nanotube Conjugatesp. 100
Layer-by-Layer Assembly of Enzymes on Carbon Nanotubesp. 117
Sustainable Biocatalytic Nanofibers: Synthesis, Characterization, and Applications of Enzyme-Coated Polymeric Nanofibersp. 129
Reactivity and Characterization of Bioengineered Metal Oxide Nanoparticlesp. 144
Nanobiocomposites
Surfactant Aggregates as Matrix Nanocontainers for Proteins (Enzymes) Entrapment and Regulationp. 156
Biomimetic Silica Encapsulation of Nanoparticles and Enzymesp. 171
A Biomimetic Process for Enzyme Immobilization within Polycation-Templated Silicap. 183
Nanoporous Sol-Gel Supports Enzymatic Hydrolysis of Chlorophyll in Organic Mediap. 199
Enzyme Encapsulation Using Nanoparticle-Assembled Capsulesp. 214
Applications of Nanoscale Biocatalysts
Highly Sensitive and Magnetically Switchable Biosensors Using Ordered Mesoporous Carbonsp. 234
Continuous-Flow Applications of Silica-Encapsulated Enzymesp. 243
Enzyme-Nanofiber Composites for Biocatalysis Applicationsp. 254
Biomimetic Synthesis of an Active H2 Catalyst Using the Ferritin Protein Cage Architecturep. 263
Carbon Nanotube Composite Electrodes for Biofuel Cellsp. 273
In Situ Characterization Techniques for Design and Evaluation of Micro- and Nano-Enzyme-Catalyzed Power Sourcesp. 289
Soybean Oil Biofuel Cell: Utilizing Lipoxygenase Immobilized by Modified Nafion" to Catalyze the Oxidation of Fatty Acids for Biofuel Cellsp. 334
Surface Patterning and Functionalization for Biomolecular Motor Nanotechnologyp. 354
Bionanotransportersp. 375
Indexes
Author Indexp. 397
Subject Indexp. 399
Table of Contents provided by Blackwell. All Rights Reserved.

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