Preface |
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xiii | |
Acknowledgments |
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xiv | |
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1 | (11) |
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1.1 Brief history of meteorological sciences |
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1 | (4) |
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1.2 Brief history of air-pollution science |
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5 | (1) |
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1.3 The merging of air-pollution and meteorological sciences |
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6 | (1) |
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1.4 Weather, climate, and air pollution |
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6 | (2) |
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8 | (1) |
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1.6 Atmospheric processes |
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8 | (4) |
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2 Atmospheric structure, composition, and thermodynamics |
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12 | (49) |
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2.1 Pressure, density, and composition |
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12 | (6) |
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2.2 Temperature structure |
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18 | (10) |
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28 | (6) |
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2.4 Changes of pressure with altitude |
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34 | (3) |
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2.5 Water in the atmosphere |
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37 | (10) |
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2.6 First law of thermodynamics |
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47 | (10) |
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57 | (1) |
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58 | (2) |
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2.9 Computer programming practice |
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60 | (1) |
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3 The continuity and thermodynamic energy equations |
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61 | (21) |
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61 | (4) |
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65 | (3) |
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3.3 Expanded continuity equations |
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68 | (10) |
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3.4 Thermodynamic energy equation |
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78 | (2) |
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80 | (1) |
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80 | (1) |
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3.7 Computer programming practice |
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81 | (1) |
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4 The momentum equation in Cartesian and spherical coordinates |
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82 | (56) |
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4.1 Horizontal coordinate systems |
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82 | (5) |
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4.2 Newton's second law of motion |
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87 | (24) |
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4.3 Applications of the momentum equation |
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111 | (24) |
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135 | (1) |
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136 | (1) |
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4.6 Computer programming practice |
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137 | (1) |
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5 Vertical-coordinate conversions |
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138 | (31) |
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5.1 Hydrostatic and nonhydrostatic models |
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138 | (5) |
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143 | (1) |
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143 | (8) |
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5.4 Sigma-pressure coordinate |
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151 | (9) |
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5.5 Sigma-altitude coordinate |
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160 | (7) |
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167 | (1) |
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167 | (1) |
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5.8 Computer programming practice |
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168 | (1) |
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6 Numerical solutions to partial differential equations |
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169 | (35) |
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6.1 Ordinary and partial differential equations |
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169 | (1) |
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170 | (1) |
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6.3 Advection-diffusion equations |
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171 | (1) |
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6.4 Finite-difference approximations |
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172 | (20) |
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6.5 Series expansion methods |
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192 | (7) |
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6.6 Finite-volume methods |
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199 | (1) |
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6.7 Advection schemes used in air-quality models |
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199 | (3) |
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202 | (1) |
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202 | (1) |
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6.10 Computer programming practice |
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203 | (1) |
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7 Finite-differencing the equations of atmospheric dynamics |
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204 | (24) |
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204 | (4) |
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7.2 The continuity equation for air |
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208 | (3) |
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7.3 The species continuity equation |
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211 | (2) |
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7.4 The thermodynamic energy equation |
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213 | (1) |
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7.5 The horizontal momentum equations |
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214 | (7) |
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7.6 The hydrostatic equation |
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221 | (1) |
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7.7 Order of calculations |
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222 | (1) |
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7.8 Time-stepping schemes |
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222 | (2) |
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224 | (1) |
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224 | (1) |
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7.11 Computer programming practice |
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225 | (1) |
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225 | (3) |
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8 Boundary-layer and surface processes |
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228 | (45) |
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8.1 Turbulent fluxes of momentum, energy, and moisture |
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228 | (2) |
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230 | (1) |
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8.3 Surface roughness lengths |
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231 | (4) |
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8.4 Parameterizations of kinematic turbulent fluxes |
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235 | (15) |
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8.5 Eddy diffusion above the surface layer |
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250 | (4) |
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8.6 Ground surface temperature and soil moisture |
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254 | (17) |
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271 | (1) |
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271 | (1) |
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8.9 Computer programming practice |
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272 | (1) |
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9 Radiative energy transfer |
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273 | (63) |
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9.1 Energy transfer processes |
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273 | (2) |
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9.2 Electromagnetic spectrum |
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275 | (8) |
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283 | (7) |
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9.4 Absorption and scattering by gases and particles |
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290 | (23) |
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313 | (3) |
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316 | (1) |
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317 | (3) |
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9.8 The radiative transfer equation |
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320 | (14) |
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334 | (1) |
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334 | (1) |
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9.11 Computer programming practice |
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335 | (1) |
10 Gas-phase species, chemical reactions, and reaction rates |
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336 | (21) |
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10.1 Atmospheric gases and their molecular structures |
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336 | (6) |
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10.2 Chemical reactions and photoprocesses |
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342 | (2) |
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344 | (2) |
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10.4 Reaction rate coefficients |
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346 | (5) |
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351 | (2) |
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353 | (2) |
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355 | (1) |
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355 | (1) |
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10.9 Computer programming practice |
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356 | (1) |
11 Urban, free-tropospheric, and stratospheric chemistry |
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357 | (61) |
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11.1 Free-tropospheric photochemistry |
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357 | (18) |
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11.2 Urban photochemistry |
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375 | (18) |
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11.3 Stratospheric photochemistry |
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393 | (22) |
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415 | (1) |
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416 | (1) |
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11.6 Computer programming practice |
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417 | (1) |
12 Methods of solving chemical ordinary differential equations |
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418 | (28) |
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12.1 Characteristics of chemical ODEs |
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418 | (3) |
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12.2 Analytical solutions to ODEs |
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421 | (1) |
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12.3 Taylor series solution to ODEs |
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421 | (1) |
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12.4 Forward Euler solution to ODEs |
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422 | (2) |
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12.5 Backward Euler solution to ODEs |
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424 | (2) |
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12.6 Simple exponential and quasi-steady-state solutions to ODEs |
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426 | (1) |
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12.7 Multistep implicit-explicit (MIE) solution to ODEs |
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427 | (5) |
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12.8 Gear's solution to ODEs |
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432 | (7) |
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12.9 Family solution to ODEs |
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439 | (3) |
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442 | (1) |
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442 | (1) |
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12.12 Computer programming practice |
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443 | (1) |
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444 | (2) |
13 Particle components, size distributions, and size structures |
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446 | (24) |
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13.1 Introduction to particles |
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446 | (1) |
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13.2 Aerosol, fog, and cloud composition |
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447 | (2) |
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13.3 Discrete size distributions |
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449 | (5) |
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13.4 Continuous size distributions |
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454 | (8) |
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13.5 Evolution of size distributions over time |
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462 | (5) |
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467 | (1) |
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468 | (1) |
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13.8 Computer programming practice |
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468 | (2) |
14 Aerosol emission and nucleation |
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470 | (24) |
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470 | (14) |
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484 | (8) |
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492 | (1) |
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493 | (1) |
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14.5 Computer programming practice |
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493 | (1) |
15 Coagulation |
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494 | (31) |
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15.1 Implicit coagulation |
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494 | (2) |
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15.2 Semiimplicit Coagulation |
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496 | (2) |
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15.3 Comparison with analytical solutions |
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498 | (2) |
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15.4 Coagulation among multiple particle distributions |
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500 | (5) |
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15.5 Particle flow regimes |
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505 | (3) |
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508 | (14) |
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522 | (1) |
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523 | (1) |
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15.9 Computer programming practice |
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523 | (2) |
16 Condensation, evaporation, deposition, and sublimation |
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525 | (28) |
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16.1 Fluxes to and from a single drop |
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525 | (3) |
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16.2 Corrections to growth parameters |
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528 | (12) |
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16.3 Fluxes to a particle with multiple components |
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540 | (1) |
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16.4 Fluxes to a population of particles |
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540 | (2) |
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16.5 Solutions to growth equations |
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542 | (3) |
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16.6 Solving homogeneous nucleation with condensation |
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545 | (2) |
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16.7 Effects of condensation on coagulation |
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547 | (1) |
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548 | (2) |
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550 | (1) |
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550 | (1) |
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16.11 Computer programming practice |
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551 | (2) |
17 Chemical equilibrium and dissolution processes |
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553 | (45) |
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553 | (1) |
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17.2 Equilibrium reactions |
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554 | (4) |
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17.3 Equilibrium relation and coefficients |
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558 | (4) |
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17.4 Forms of equilibrium-coefficient equations |
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562 | (3) |
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17.5 Mean binary solute activity coefficients |
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565 | (2) |
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17.6 Temperature dependence of binary solute activity coefficients |
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567 | (1) |
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17.7 Mean mixed solute activity coefficients |
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568 | (2) |
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570 | (4) |
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17.9 Solid formation and deliquescence relative humidity |
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574 | (1) |
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17.10 Example equilibrium problem |
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575 | (2) |
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17.11 Mass-flux iteration method |
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577 | (2) |
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17.12 Analytical equilibrium iteration method |
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579 | (3) |
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17.13 Equilibrium solver results |
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582 | (1) |
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17.14 Nonequilibrium between gases and particles |
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583 | (11) |
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594 | (2) |
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596 | (1) |
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17.17 Computer programming practice |
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596 | (2) |
18 Cloud thermodynamics and dynamics |
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598 | (47) |
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18.1 Fog and cloud types and formation mechanisms |
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598 | (4) |
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18.2 Moist adiabatic and pseudoadiabatic processes |
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602 | (4) |
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18.3 Cloud development by free convection |
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606 | (2) |
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608 | (2) |
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18.5 Vertical momentum equation in a cloud |
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610 | (2) |
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18.6 Convective available potential energy |
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612 | (1) |
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18.7 Cumulus parameterizations |
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612 | (2) |
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614 | (28) |
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642 | (1) |
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643 | (1) |
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18.11 Computer programming practice |
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643 | (2) |
19 Irreversible aqueous chemistry |
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645 | (16) |
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19.1 Significance of aqueous chemical reactions |
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645 | (1) |
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19.2 Mechanisms of converting S(IV) to S(VI) |
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646 | (6) |
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19.3 Diffusion within a drop |
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652 | (2) |
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19.4 Solving growth and aqueous chemical ODEs |
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654 | (5) |
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659 | (1) |
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659 | (1) |
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19.7 Computer programming practice |
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660 | (1) |
20 Sedimentation, dry deposition, and air-sea exchange |
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661 | (20) |
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661 | (4) |
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665 | (5) |
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20.3 Dry deposition and sedimentation calculations |
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670 | (2) |
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20.4 Air-sea flux of carbon dioxide and other gases |
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672 | (7) |
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679 | (1) |
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679 | (1) |
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20.7 Computer programming practice |
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679 | (2) |
21 Model design, application, and testing |
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681 | (28) |
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21.1 Steps in model formulation |
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681 | (19) |
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21.2 Example model simulations |
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700 | (7) |
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707 | (1) |
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707 | (1) |
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21.5 Computer programming practice |
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707 | (2) |
Appendix A Conversions and constants |
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709 | (5) |
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709 | (1) |
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709 | (1) |
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709 | (1) |
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A.4 Temperature conversions |
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710 | (1) |
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710 | (1) |
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710 | (1) |
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710 | (1) |
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710 | (1) |
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710 | (1) |
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711 | (3) |
Appendix B Tables |
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714 | (38) |
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B.1 Standard atmospheric variables versus altitude |
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714 | (1) |
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B.2 Solar irradiance at the top of the atmosphere |
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715 | (1) |
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B.3 Chemical symbols and structures of gases |
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716 | (12) |
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728 | (10) |
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B.5 Chemicals involved in equilibrium and aqueous reactions |
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738 | (2) |
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740 | (1) |
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B.7 Equilibrium reactions and rate coefficients |
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741 | (2) |
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B.8 Irreversible aqueous reactions |
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743 | (3) |
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B.9 Solute activity coefficient data |
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746 | (2) |
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748 | (1) |
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B.11 Surface resistance data |
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749 | (2) |
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B.12 More surface resistance data |
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751 | (1) |
References |
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752 | (32) |
Index |
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784 | |