Heterogeneous Catalysis and Fine Chemicals IV Vol. 108 : Proceedings of the 4th International Symposium on Heterogeneous Catalysis and Fine Chemicals, Basel, Switzerland, September 8-12, 1996

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Format: Hardcover
Pub. Date: 1997-06-01
Publisher(s): Elsevier Science Serials
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Summary

After three meetings in Poitiers, France, the 4th International Symposium on Heterogeneous Catalysis and Fine Chemicals was held under the auspices of the New Swiss Chemical Society in Basel, Switzerland. Fundamental as well as applied contributions on the use of heterogeneous catalysis for the preparation of fine chemicals were presented and discussed. The program consisted of 4 plenary lectures, 28 oral contributions and around 90 posters covering a broad range of reactions and catalytic aspects. 82 of these contributions are collected in the present proceedings, grouped into the following 8 topical areas: - Industrial and engineering problems (7 contributions) - Alkylation and acylation reactions (11 contributions) - Enantio- and diastereoselective hydrogenation reactions (9 contributions) - Chemoselective hydrogenation reactions (12 contributions) - Oxidation reactions (14 contributions) - Immobilized and encapsulated complex catalysts (12 contributions) - Zeolite and clay catalysts (12 contributions) - Miscellaneous topics (5 contributions)

Table of Contents

Foreword XIII(1)
Scientific Committee XIV(1)
Organizing Committee XIV(1)
Financial Support XV
Industrial and Engineering Problems 1(66)
1 Homogeneous catalysis for fine chemicals synthesis - new trends and perspectives
1(16)
M. Beller
2 Catalysis for agrochemicals: the case history of the DUAL herbicide
17(14)
R. R. Bader
H. U. Blaser
3 Heterogeneous vs. homogeneous catalysis in manufacturing of terbinafine - a case study for route selection of an industrial process
31(6)
U. Beutler
C. Fleury
P. C. Fiinfschilling
G. Penn
Th. Ryser
B. Schenkel
4 Multiple use of palladium in a homogeneous and a consecutive heterogeneous catalytic reaction
37(4)
P. Baumeister
W. Meyer
K. Oertle
G. Seifert
U. Siegrist
H. Steiner
5 The optimization of the catalytic hydrogenation of hydroxybenzamidines to benzamidines
41(6)
M. G. Scaros
P. K. Yonan
S. A. Laneman
6 Catalytic hydrogenation reactors for the fine chemicals industries; their design and operation
47(12)
K. R. Westerterp
E. J. Molga
K. B. van Gelder
7 Selective catalytic hydrogenation of 2-butyne-1,4-diol to cis-2-butene-1,4-diol in mass transfer efficient slurry reactors
59(8)
J. M. Winterbottom
H. Marwan
J. Viladevall
S. Sharma
S. Raymahasay
Alkylation and Acylation Reactions 67(90)
8 Replacing liquid acids in fine chemical synthesis by sulfonated polysiloxanes as solid acids and as acidic supports for precious metal catalysts
67(8)
St. Wieland
P. Panster
9 Amine functions linked to MCM-41-type silicas as a new class of solid base catalysts for condensation reactions
75(8)
M. Lasperas
T. Llorett
L. Chaves
I. Rodriguez
A. Cauvel
D. Brunel
10 Modified clay catalysts for acylation of crown compounds
83(8)
S. Bekassy
K. Biro
T. Cseri
B. Agai
F. Figueras
11 Acylation of aromatics over a HBEA Zeolite; effect of solvent and of acylating agent
91(8)
F. Jayat
M. J. Sabater Picot
D. Rohan
M. Guisnet
12 Zeolite-catalysed acetylation of alkenes with acetic anhydride
99(8)
K. Smith
Zhao Zhenhua
L. Delaude
P. K. G. Hodgson
13 Influence of the acidity and of the pore structure of zeolites on the alkylation of toluene by 1-heptene
107(8)
P. Magnoux
A. Mourran
S. Bernard
M. Guisnet
14 Reductive O-and N-alkylations; alternative catalytic methods to nucleophilic substitution
115(8)
F. Fache
V. Bethmont
L. Jacquot
F. Valot
A. Milenkovic
M. Lemaire
15 N-Methylation of aniline over AIPO(4) and AIPO(4)-metal oxide catalysts
123(8)
F. M. Bautista
J. M. Campelo
A. Garcia
D. Luna
J. M. Marinas
A. A. Romero
16 Preparation of symmetrical and mixed secondary alkylamines over Raney nickel and supported copper catalysts
131(8)
S. Gobolos
M. Hegedus
E. Talas
J. L. Margitfalvi
17 Synthesis of dimethylethylamine from ethylamine and methanol over copper catalysts
139(10)
Y. Pouilloux
V. Doidy
S. Hub
J. Kervennal
J. Barrault
18 Catalyst acid base properties regulation to control the selectivity in gasphase methylation of catechol
149(8)
L. Kiwi-Minsker
S. Porchet
R. Doepper
A. Renken
Enantio- and Diastereoselective Hydrogenation Reactions 157(74)
19 Enantioselective hydrogenation of ethyl-pyruvate and isophorone over modified Pt and Pd catalysts
157(10)
A. Tungler
K. Fodor
T. Mathe
R. A. Sheldon
20 Controlling the enantioselective hydrogenation of ethyl pyruvate using zeolites as catalyst support
167(8)
K. Morgenschweis
E. Polkiehn
W. Reschetilowski
21 Kinetic modeling of the ligand accelerated catalysis in the enantioselective hydrogenation of ethyl pyruvate; influence of solvents, catalysts and additives
175(8)
H. U. Blaser
D. Imhof
M. Studer
22 Modeling of kinetically coupled selective hydrogenation reactions: kinetic rationalization of pressure effects on enantioselectivity
183(8)
J. Wang
C. LeBlond
C. F. Orella
Y. Sun
J. S. Bradley
D. G. Blackmond
23 Enantioselective hydrogenation of (E)-XXX-phenylcinnamic acid on cinchonidine-modified palladium catalysts: influence of support
191(8)
Y. Nitta
K. Kobiro
Y. Okamoto
24 Enantio-differentiating hydrogenation of 3-alkanones with asymmetrically modified fine nickel powder
199(8)
T. Osawa
T. Harada
A. Tai
O. Takayasu
I. Matsuura
25 Diastereoselective hydrogenation of a prostaglandin intermediate over Rusupported on different molecular sieves
207(8)
F. Cocu
S. Coman
C. Tanase
D. Macovei
V. I. Parvulescu
26 Diastereoselective hydrogenation of substitued aromatics on supported rhodium catalysts: influence of support and of thermal treatment
215(8)
M. Besson
P. Gallezot
C. Pinel
S. Neto
27 Stereoselective reductions of aromatic compounds
223(8)
E. Auer
A. Freund
P. Panster
G. Stein
Th. Tacke
Chemoselective Hydrogenation Reactions 231(98)
28 Selective reduction of nitro groups in aromatic azo compounds
231(8)
M. Lauwiner
R. Roth
P. Rys
J. Wissmann
29 Selective catalytic hydrogenation of 2,4-dinitrotoluene to nitroaryl-hydroxylamines on supported metal catalysts
239(8)
M. G. Musolino
C. Milone
G. Neri
L. Bonaccorsi
R. Pietropaolo
S. Galvagno
30 Kinetics and pathways of selective hydrogenation of 1-(4-nitrobenzyl)-1,2,4-triazole
247(8)
C. LeBlond
J. Wang
R. D. Larsen
C. J. Orella
A. L. Forman
F. P. Gortsema
T. R. Verhoeven
Y. K. Sun
31 Design of selective 1-ethyl-2-nitromethylenepyrrolidine hydrogenation for pharmaceuticals production
255(8)
V. A. Semikolenov
I. L. Simakova
A. V. Golovin
O. A. Burova
N. M. Smirnova
32 Kinetic study of a nitroaliphatic compound hydrogenation
263(10)
V. Dubois
G. Jannes
P. Verhasselt
33 Kinetics of the hydrogenation of citral over supported Ni catalyst
273(8)
P. Maki-Arvela
L. -P. Tiainen
R. Gil
T. Salmi
34 Selective hydrogenation of XXX, XXX-unsaturated aldehydes to allylic alcohols over supported monometallic and bimetallic Ag catalysts
281(8)
P. Claus
P. Kraak
R. Schodel
35 Surface organometallic chemistry on metals; selective hydrogenation of acetophenone on modified rhodium catalyst
289(8)
F. Humblot
M. A. Cordonnier
C. Santini
B. Didillon
J. P. Candy
J. M. Basset
36 Use of Ni containing anionic clay minerals as precursors of catalysts for the hydrogenation of nitriles
297(8)
D. Tichit
F. Medina
R. Durand
C. Mateo
B. Coq
J. E. Sueiras
P. Salagre
37 The effect of co-adsorbates on activity/selectivity in the hydrogenation of aromatic alkynes
305(8)
S. D. Jackson
H. Hardy
G. J. Kelly
L. A. Shaw
38 Simple preparation of bimetallic palladium-copper catalysts for selective liquid phase semihydrogenation of functionalized acetylenes and propargylic alcohols
313(8)
M. P. R. Spee
D. M. Grove
G. van Koten
J. W. Geus
39 Catalytic hydrogenation by polymer stabilized rhodium
321(8)
G. W. Busser
J. G. van Ommen
J. A. Lercher
Oxidation Reactions 329(108)
40 Epoxidation of cycloalkenones over amorphous titania-silica aerogels
329(8)
R. Hutter
T. Mallat
A. Baiker
41 Selective aerobic epoxidation of olefins over NaY and NaZSM-5 zeolites containing transition metal ions
337(8)
O. Kholdeeva
A. V. Tkachev
V. N. Romannikov
I. V. Khavrutskii
K. I. Zamaraev
42 Effect of preparation methods of titania silicas on their catalytic activities in the oxidation of olefins
345(8)
M. Toba
S. Niwa
H. Shimada
F. Mizukami
43 Heterogeneous catalysts from organometallic precursors: how to design isolated, stable and active sites; applications to zirconium catalyzed organic reactions
353(8)
A. Choplin
B. Coutant
C. Dubuisson
P. Leyrit
C. McGill
F. Quignard
R. Teissier
44 Selective sulfoxidation of thioethers on Ti-containing zeolites under mild conditions
361(8)
V. Hulea
P. Moreau
F. Di Renzo
45 Allylic oxidation of cyclohexene catalysed by metal exchanged zeolite Y
369(8)
O. B. Ryan
D. E. Akporiaye
K. H. Holm
M. Stocker
46 Ammoxidation of methylaromatics over NH(4)(+)-containing vanadium phosphate catalysts - new mechanistic insights
377(8)
A. Martin
A. Bruckner
Y. Zhang
B. Lucke
47 Hydrogen peroxide oxidation of methyl XXX-D-glucopyranoside, sucrose and XXX, XXX-trehalose with Ti-MCM-41
385(6)
E. J. M. Mombarg
S. J. M. Osnabrug
F. van Rantwijk
H. van Bekkum
48 On the role of bismuth-based alloys in carbon-supported bimetallic Bi-Pd catalysts for the selective oxidation of glucose to gluconic acid
391(8)
M. Wenkin
C. Renard
P. Ruiz
B. Delmon
M. Devillers
49 Selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxaldehyde in the presence of titania supported vanadia catalysts
399(8)
C. Moreau
R. Durand
C. Pourcheron
D. Tichit
50 Dehydrogenation of methoxyisopropanol to methoxyacetone on supported bimetallic Cu-Zu catalysts
407(8)
M. V. Landau
S. B. Kogan
M. Herskowitz
51 Butadione synthesis by dehydrogenation and oxidative dehydrogenation of 2,3-butanediol
415(6)
G. V. Isagulyants
I. P. Belomestnykh
52 Phase transition of crystalline XXX-Te(2)MoO(7) to the vitreous XXX-form, surface composition, and activity in the vapor-phase selective oxidation of ethyl lactate to pyruvate over TeO(2)-MoO(3) catalysts
421(8)
H. Hayashi
S. Sugiyama
T. Moriga
N. Masaoka
A. Yamamoto
53 Selective oxidation with air of glyceric to hydroxypyruvic acid anu tartronic to mesoxalic acid on PtBi C catalysts
429(8)
P. Fordham
M. Besson
P. Gallezot
Immobilized and Encapsulted Complex Catalysts 437(94)
54 PDMS occluded Ti-MCM-41 as an improved olefin epoxidation catalyst
437(8)
I. F. J. Vankelecom
N. M. F. Moens
K. A. L. Vercruysse
R. F. Parton
P. A. Jacobs
55 Epoxidation with manganese N,N-bis (2-pyridinecarboxamide) complexes encapsulated in Zeolite Y
445(8)
P. P. Knops-Gerrits
M. L'abbe
P. A. Jacobs
56 Selective oxidation of benzyl alcohol on a zeolite ship-in-a-bottle complex
453(8)
A. Zsigmond
F. Notheisz
Z. Frater
J. E. Backvall
57 Oxidation of pinane using zeolite encapsulated metal phthalocyanine catalysts
461(8)
A. A. Valente
J. Vital
58 Hydrogenation of carbonyl groups containing compounds over Pt(II)-salen complexes occluded in zeolites
469(8)
W. Kahlen
A. Janssen
W. F. Holderich
59 Novel clay intercalated metal catalysts: a study of the hydrogenation of styrene and 1-octene on clay intercalated Pd catalysts
477(8)
A. Mastalir
F. Notheisz
Z. Kiraly
M. Bartok
I. Dekany
60 Catalytic enantioselective addition of diethylzinc to benzaldehyde induced by immobilized ephedrine: comparison of silica and MCM-41 type mesoporous silicates as supports
485(8)
N. Bellocq
D. Brunel
M. Lasperas
P. Moreau
61 The immobilization of sulfonated Ru-BINAP chloride by anion exchange on layered double hydroxides
493(8)
D. Tas
D. Jeanmart
R. F. Parton
P. A. Jacobs
62 Regiospecific hydrosilylation of styrene by rhodium complexes heterogenised on modified USY-zeolites
501(8)
A. Corma
M. I. de Dios
M. Iglesias
F. Sanchez
63 Polymer-supported Al and Ti species as catalysts for Diels-Alder reactions
509(8)
B. Altava
M. I. Burguete
J. M. Fraile
J. I. Garcia
S. V. Luis
J. A. Mayoral
A. J. Royo
R. V. Salvador
64 Molecular imprinting; polymerised catalytic complexes in asymmetric catalysis
517(6)
F. Locatelli
P. Gamez
M. Lemaire
65 Environmentally friendly catalysis of liquid phase organic reactions using chemically modified mesoporous materials
523(8)
A. J. Butterworth
J. H. Clark
A. Lambert
D. J. Macquarrie
S. J. Tavener
Zeolite and Clay Catalysts 531(94)
66 Meerwein-Ponndorf-Verley and Oppenauer reactions catalysed by heterogeneous catalysts
531(8)
E. J. Creyghton
J. Huskens
J. C. van der Waal
H. van Bekkum
67 Selective synthesis of monoglycerides from glycerol and oleic acid in the presence of solid catalysts
539(8)
S. Abro
Y. Pouilloux
J. Barrault
68 Zeolite-catalysed hydrolysis of aromatic amides
547(8)
B. Gigante
C. Santos
M. J. Marcelo-Curto
C. Coutanceau
J. M. Silva
F. Alvarez
M. Guisnet
E. Selli
L. Forni
69 Hydration of XXX-pinene and camphene over USY zeolites
555(8)
H. Valente
J. Vital
70 Dehydration of 2-(2-hydroxyethyl)-pyridine to 2-vinyl-pyridine over solid acid catalysts
563(8)
L. Forni
D. Moscotti
E. Selli
I. Belegridi
M. Guisnet
D. Rohan
B. Gigante
C. Coutanceau
J. M. Silva
F. Alvarez
71 The use of heterogeneous copper catalysts in cyclopropanation reactions
571(8)
J. M. Fraile
B. Garcia
J. I. Garcia
J. A. Mayoral
F. Figueras
72 Reaction between haloaromatics over Cu-HZSM-5 zeolite; mechanistic study
579(8)
S. Vol
L. Vivier
G. Perot
73 Selective isomerization of XXX-pinene oxide with heterogeneous catalysts
587(8)
A. T. Liebens
C. Mahaim
W. F. Holderich
74 Reactions of 2,2-dimethy 1-1,3-propanediol with zeolites: correlation of selectivity with acidity
595(8)
H. U. Blaser
B. Casagrande
B. Siebenhaar
75 Clay-catalyzed reactions of imidazole and benzimidazoles with propiolic esters
603(6)
M. Balogh
C. Gonczi
I. Hermecz
76 Selective synthesis of cyclohexylcyclohexanone on bifunctional zeolite catalysts; influence of the metal and of the pore structure
609(8)
F. Alvarez
A. I. Silva
F. Ramoa Ribeiro
G. Giannetto
M. Guisnet
77 Solid acid catalyzed disproportionation and alkylation of alkylsilanes
617(8)
T. Yamaguchi
T. Yamada
M. Shibata
T. Tsuneki
M. Ookawa
Miscellaneous Topics 625(40)
78 Intramolecular ene reactions promoted by mixed cogels
625(8)
N. Ravasio
M. Antenori
F. Babudri
M. Gargano
79 Rh(3+)-diamine complexes intercalated in XXX-and XXX-zirconium hydrogen phosphate as stable and effective catalysts for the conversion of aniline or nitrohenzene to carbamates and or N,N'-diphenylurea; Part 3
633(8)
P. Giannoccaro
S. Doronzo
C. Ferragina
80 1,4-Butanediol conversion routes over bifunctional supported Co-Zn catalyst
641(8)
L. Leite
S. Kruc
Zh. Yuskovets
V. Stonkus
M. Fleisher
E. Lukevics
J. Stoch
M. Mikalayczyk
81 Preparation of solid superbase catalyst and its application to the synthesis of fine chemicals
649(8)
G. Suzukamo
M. Fukao
T. Hibi
K. Tanaka
M. Minobe
82 Synthesis of delicious peptide fragments catalyzed by immobilized proteases
657(8)
M. D. Romero
J. Aguado
M. J. Guerra
G. Alvaro
R. Navarro
E. Rubio
Author Index 665(4)
Other volumes in the series 669

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