Summary
Twenty years ago author Kurt Stern produced four monographs for the National Bureau of Standards on the high-temperature properties of inorganic salts containing oxyanions. Although relied upon by scientists and engineers around the world, these monographs have now become increasingly difficult to access and increasingly outdated.High Temperature Properties and Thermal Decomposition of Inorganic Salts with Oxyanions unifies, expands upon, and brings up-to-date those standard-setting documents. It offers both qualitative and quantitative information on the behavior and properties of approximately 300 compounds, complete with thermodynamic tables of decomposition equilibria and information regarding decomposition kinetics. For each class of compounds, an existence chart in the form of a periodic table tells you at a glance which compounds are known to exist, those whose existence is uncertain, and those about which nothing is known. Supplementary tables give information about phase transitions and densities in both solid and liquid phases.Within this single volume, the author provides a comprehensive, critical review of the high-temperature properties of all the major classes of inorganic salts with oxyanions. If you work with materials or processes that involve salts at elevated temperatures, you now have an authoritative resource that obviates the need to perform extensive literature searches, data evaluations, and thermodynamic calculations-and saves you time.
Author Biography
Dr. Kurt H. Stern obtained his B.A. degree in chemistry from Drew University in Madison, NJ in 1948, his M.S. degree in physical chemistry from the University of Michigan in 1950, and a Ph.D. from Clark University under Prof. Arthur Martell in 1953. He then joined the faculty of the University of Arkansas. In 1959, while spending a sabbatical year at the National Bureau of Standards in Washington, he was asked to join the staff and to start a program in molten salt electrochemistry. While at NBS he became involved in the formation of the National Standards Reference Data Program. In 1969 he moved to the Naval Research Laboratory where he continued his research. He retired from active research in 1991
Table of Contents
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1 | (1) |
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2 | (1) |
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3 | (1) |
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3 | (1) |
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Kinetics of Thermal Decomposition |
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4 | (11) |
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4 | (1) |
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Mechanism of Endothermic Solid State Decomposition |
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4 | (1) |
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5 | (1) |
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5 | (1) |
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6 | (2) |
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Surface Area Changes during Decomposition |
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8 | (1) |
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The Effect of Pressure on Rate |
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9 | (2) |
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11 | (1) |
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The Effect of Preparation Method on Rate |
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12 | (1) |
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The Effect of Heat Transfer on Rate |
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12 | (1) |
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The Influence of Crystal Defect Structure on Decomposition Rate |
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13 | (1) |
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13 | (2) |
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15 | (1) |
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Structure of the Carbonate Ion |
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15 | (1) |
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General Features of Carbonate Decomposition |
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15 | (1) |
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16 | (1) |
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16 | (1) |
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16 | (1) |
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The Individual Carbonates |
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17 | (36) |
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17 | (1) |
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17 | (1) |
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17 | (1) |
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17 | (1) |
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17 | (1) |
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17 | (1) |
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18 | (1) |
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18 | (1) |
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18 | (1) |
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19 | (1) |
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19 | (1) |
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19 | (1) |
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20 | (1) |
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20 | (1) |
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20 | (1) |
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20 | (1) |
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20 | (1) |
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20 | (1) |
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21 | (1) |
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21 | (1) |
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21 | (1) |
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21 | (1) |
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22 | (1) |
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22 | (28) |
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50 | (3) |
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53 | (1) |
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53 | (6) |
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53 | (1) |
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54 | (1) |
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54 | (1) |
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54 | (1) |
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54 | (1) |
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54 | (1) |
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55 | (1) |
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55 | (1) |
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55 | (1) |
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55 | (1) |
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55 | (1) |
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55 | (1) |
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56 | (1) |
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56 | (1) |
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56 | (1) |
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56 | (2) |
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58 | (1) |
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59 | (1) |
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59 | (1) |
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60 | (75) |
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60 | (1) |
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60 | (1) |
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60 | (1) |
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60 | (1) |
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61 | (1) |
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61 | (1) |
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61 | (1) |
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61 | (1) |
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61 | (1) |
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62 | (1) |
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62 | (1) |
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63 | (1) |
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63 | (1) |
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63 | (1) |
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63 | (2) |
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65 | (1) |
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65 | (1) |
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65 | (1) |
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65 | (1) |
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66 | (1) |
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66 | (1) |
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66 | (1) |
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66 | (1) |
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66 | (2) |
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68 | (1) |
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68 | (1) |
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68 | (1) |
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68 | (1) |
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68 | (1) |
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68 | (1) |
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68 | (1) |
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68 | (1) |
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68 | (1) |
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68 | (1) |
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69 | (1) |
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69 | (1) |
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69 | (1) |
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69 | (1) |
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69 | (1) |
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69 | (1) |
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69 | (1) |
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69 | (1) |
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70 | (1) |
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70 | (1) |
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70 | (1) |
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70 | (1) |
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70 | (1) |
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70 | (1) |
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71 | (1) |
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71 | (1) |
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71 | (1) |
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72 | (60) |
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132 | (3) |
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Gaseous Equilibria in the N-O System |
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135 | (1) |
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135 | (1) |
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136 | (3) |
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136 | (1) |
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137 | (2) |
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Individual Nitrites and Nitrates |
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139 | (46) |
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139 | (1) |
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139 | (1) |
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139 | (1) |
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140 | (1) |
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140 | (1) |
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141 | (1) |
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141 | (1) |
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141 | (1) |
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141 | (1) |
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141 | (1) |
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141 | (1) |
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142 | (1) |
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142 | (1) |
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142 | (1) |
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142 | (1) |
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142 | (1) |
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143 | (1) |
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143 | (1) |
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143 | (1) |
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143 | (1) |
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143 | (1) |
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143 | (1) |
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143 | (1) |
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143 | (1) |
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143 | (1) |
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144 | (1) |
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144 | (1) |
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144 | (1) |
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144 | (1) |
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144 | (1) |
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145 | (1) |
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145 | (1) |
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145 | (1) |
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146 | (1) |
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146 | (1) |
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146 | (1) |
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146 | (1) |
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146 | (1) |
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146 | (1) |
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147 | (1) |
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147 | (1) |
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147 | (1) |
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147 | (1) |
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147 | (1) |
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147 | (1) |
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147 | (1) |
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147 | (1) |
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148 | (1) |
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148 | (1) |
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148 | (1) |
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148 | (1) |
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149 | (1) |
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149 | (1) |
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149 | (1) |
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149 | (1) |
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150 | (1) |
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150 | (1) |
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150 | (1) |
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150 | (1) |
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150 | (1) |
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150 | (1) |
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151 | (1) |
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151 | (1) |
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151 | (1) |
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152 | (1) |
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152 | (1) |
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153 | (1) |
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153 | (1) |
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153 | (1) |
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153 | (1) |
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153 | (1) |
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153 | (1) |
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153 | (28) |
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181 | (4) |
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185 | (1) |
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185 | (1) |
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185 | (1) |
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Chemistry of the Halogen Oxysalts |
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185 | (4) |
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187 | (2) |
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189 | (1) |
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Classes of Oxychlorin Salts |
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189 | (3) |
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189 | (1) |
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190 | (1) |
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191 | (1) |
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192 | (29) |
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192 | (1) |
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192 | (1) |
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192 | (1) |
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193 | (1) |
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193 | (1) |
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193 | (1) |
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193 | (1) |
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194 | (1) |
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194 | (1) |
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194 | (1) |
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194 | (1) |
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194 | (1) |
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194 | (1) |
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195 | (1) |
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195 | (1) |
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195 | (1) |
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195 | (1) |
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196 | (1) |
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196 | (1) |
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196 | (1) |
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196 | (1) |
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196 | (1) |
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197 | (1) |
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197 | (1) |
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197 | (1) |
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197 | (1) |
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197 | (1) |
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197 | (1) |
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197 | (1) |
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197 | (1) |
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198 | (1) |
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198 | (1) |
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198 | (1) |
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199 | (1) |
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199 | (1) |
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199 | (1) |
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199 | (1) |
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200 | (1) |
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200 | (1) |
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200 | (1) |
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200 | (1) |
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200 | (1) |
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200 | (1) |
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200 | (1) |
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200 | (1) |
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201 | (1) |
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201 | (1) |
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201 | (1) |
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201 | (1) |
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202 | (1) |
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203 | (1) |
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203 | (1) |
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203 | (1) |
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203 | (1) |
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204 | (1) |
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204 | (1) |
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204 | (1) |
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204 | (1) |
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205 | (1) |
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205 | (1) |
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205 | (1) |
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205 | (1) |
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206 | (1) |
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206 | (1) |
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206 | (1) |
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206 | (1) |
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207 | (1) |
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208 | (1) |
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208 | (1) |
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208 | (1) |
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208 | (1) |
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208 | (1) |
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208 | (1) |
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208 | (1) |
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209 | (1) |
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209 | (1) |
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209 | (1) |
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209 | (1) |
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209 | (1) |
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209 | (1) |
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209 | (1) |
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209 | (1) |
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209 | (1) |
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210 | (8) |
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218 | (3) |
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221 | (1) |
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Classes of Oxybromine Salts |
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221 | (3) |
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221 | (1) |
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221 | (3) |
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224 | (1) |
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Individual Bromine Oxysalts |
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224 | (13) |
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224 | (1) |
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224 | (1) |
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225 | (1) |
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225 | (1) |
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225 | (1) |
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225 | (1) |
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225 | (1) |
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225 | (1) |
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226 | (1) |
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226 | (1) |
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226 | (1) |
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226 | (1) |
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226 | (1) |
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226 | (1) |
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226 | (1) |
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226 | (1) |
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226 | (1) |
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226 | (1) |
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227 | (1) |
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227 | (1) |
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227 | (1) |
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227 | (1) |
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227 | (1) |
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227 | (1) |
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227 | (1) |
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228 | (1) |
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228 | (1) |
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228 | (1) |
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228 | (1) |
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228 | (1) |
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228 | (1) |
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228 | (1) |
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228 | (1) |
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229 | (1) |
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229 | (1) |
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229 | (1) |
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229 | (1) |
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229 | (1) |
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229 | (1) |
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229 | (1) |
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230 | (1) |
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230 | (1) |
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230 | (1) |
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230 | (1) |
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230 | (1) |
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230 | (1) |
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231 | (3) |
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234 | (3) |
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237 | (1) |
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Classes of Oxyiodine Salts |
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237 | (4) |
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237 | (1) |
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237 | (3) |
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240 | (1) |
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254 | |
|
|
|
254 | |
|
|
|
254 | |
|
|
|
254 | |
|
|
|
254 | |
|
|
|
255 | |
|
|
|
255 | |
|
|
|
255 | |
|
|
|
263 | |