HPLC of Polymers,9783540616894

HPLC of Polymers

by ;
ISBN13: 9783540616894
ISBN10: 3540616896
Format: Nonspecific Binding
Pub. Date: 2012-12-06
Publisher(s): Springer Nature
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Summary

Describes the experimental approach to the chromatographic analysis of polymers. Discusses different chromatographic methods, their theoretical background, equipment, experimental procedures and applications. DLC: Polymers - Analysis.

Table of Contents

1 INTRODUCTION
1(16)
H. Pasch
1.1 The Molecular Structure of Polymers
1(4)
1.2 Molar Mass Distribution
5(1)
1.3 Chemical Composition Distribution
6(3)
1.4 Functionality Type Distribution
9(2)
1.5 Polymer Solution Properties
11(4)
References
15(2)
2 THERMODYNAMICS OF POLYMER CHROMATOGRAPHY
17(8)
H. Pasch
2.1 Entropic and Enthalpic Interactions
17(1)
2.2 Size Exclusion Mode
18(1)
2.3 Adsorption Mode
19(1)
2.4 Critical Mode
20(2)
References
22(3)
3 EQUIPMENT AND MATERIALS
25(16)
B. Trathnigg
3.1 Solvent Delivery
25(1)
3.2 Injection Systems
26(1)
3.3 Columns
26(4)
3.3.1 Dimensions
27(1)
3.3.2 Stationary Phases
28(2)
3.4 Mobile Phases
30(1)
3.5 Detectors
31(7)
3.5.1 Concentration-Sensitive Detectors
31(4)
3.5.2 Molar Mass-Sensitive Detectors
35(3)
References
38(3)
4 SIZE EXCLUSION CHROMATOGRAPHY
41(40)
B. Trathnigg
4.1 Concerns in SEC
42(2)
4.2 Equipment and Materials
44(4)
4.3 Data Acquisition and Processing
48(12)
4.3.1 Operation of an SEC System
49(3)
4.3.2 Calibration
52(5)
4.3.3 Quantification in SEC
57(3)
4.4 Analysis of Homopolymers by SEC
60(5)
4.4.1 Calibration of the Chromatographic System
60(3)
4.4.2 Analysis of a Polystyrene Homopolymer
63(2)
4.5 Analysis of Copolymers by SEC with Dual Detection
65(7)
4.6 Analysis of Oligomers by SEC
72(6)
4.6.1 Analysis of Fatty Alcohol Ethoxylates
72(4)
4.6.2 Analysis of Block Copolymers of Ethylene Oxide and Propylene Oxide
76(2)
References
78(3)
5 LIQUID ADSORPTION CHROMATOGRAPHY
81(38)
H. Pasch
5.1 Peculiarities
81(7)
5.2 Equipment and Materials
88(4)
5.3 Data Acquisition and Processing
92(2)
5.4 Analysis of Oligomers
94(8)
5.4.1 Separation of Octylphenol Ethoxylate by Isocratic Elution
94(5)
5.4.2 Separation of Oligostyrene by Gradient Elution
99(3)
5.5 Fractionation of Copolymers
102(14)
5.5.1 Analysis of Graft Copolymers of Ethylene-Propene-Diene Rubber and Methyl Methacrylate
102(5)
5.5.2 Analysis of Copolymers of Decyl and Methyl Methacrylate
107(5)
5.5.3 Analysis of Random Copolymers of Styrene and Ethyl Acrylate
112(4)
References
116(3)
6 LIQUID CHROMATOGRAPHY AT THE CRITICAL POINT OF ADSORPTION
119(72)
H. Pasch
6.1 Peculiarities
119(2)
6.2 Equipment and Materials
121(3)
6.3 Data Acquisition and Processing
124(1)
6.4 Separation of Functional Homopolymers
125(26)
6.4.1 Principles and Limitations
125(3)
6.4.2 Analysis of Polyethylene Oxides
128(9)
6.4.3 Analysis of Aliphatic Polyesters
137(6)
6.4.4 Analysis of Benzyloxy-Terminated Poly(1,3,6-trioxocane)s
143(4)
6.4.5 Analysis of Hydroxyethylmethacryloyl-Terminated Poly(1,3,6-trioxocane)s
147(4)
6.5 Separation of Block Copolymers
151(25)
6.5.1 Principles and Limitations
151(5)
6.5.2 Analysis of Poly(styrene-block-methyl methacrylate)s
156(8)
6.5.3 Analysis of Poly(decyl methacrylate-block methyl methacrylate)s
164(6)
6.5.4 Analysis of Poly(ethylene oxide-block-propylene oxide-block-ethylene oxide)
170(6)
6.6 Analysis of Polymer Blends
176(13)
6.6.1 Principles and Limitations
176(2)
6.6.2 Analysis of Blends of Polystyrene and Poly(methyl methacrylate)
178(4)
6.6.3 Analysis of Blends of PMMA and Poly(n-butyl methacrylate)
182(4)
6.6.4 Analysis of Blends of Containing Poly(t-butyl methacrylate)
186(3)
References
189(2)
7 TWO-DIMENSIONAL LIQUID CHROMATOGRAPHY
191(30)
H. Pasch
7.1 Peculiarities
191(4)
7.2 Equipment and Materials
195(5)
7.3 Data Acquisition and Processing
200(3)
7.4 Separation of a Technical Poly(ethylene oxide)
203(5)
7.5 Separation of Block Copolymers of Styrene and Methyl Methacrylate
208(5)
7.6 Analysis of Styrene-Butadiene Star Polymers
213(6)
References
219(2)
SUBJECT INDEX 221

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