Membrane Gas Separation

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Format: eBook
Pub. Date: 2010-06-01
Publisher(s): Wiley
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Summary

Gas separation membranes offer a number of benefits over other separation technologies, and they play an increasingly important role in reducing the environmental impacts and costs of many industrial processes.This book describes recent and emerging results in membrane gas separation, including highlights of nanoscience and technology, novel polymeric and inorganic membrane materials, new membrane approaches to solve environmental problems e.g. greenhouse gases, aspects of membrane engineering, and recent achievements in industrial gas separation. It includes:Hyperbranched polyimides, amorphous glassy polymers and perfluorinated copolymers Nanocomposite (mixed matrix) membranes Polymeric magnetic membranes Sequestration of CO2 to reduce global warming Industrial applications of gas separationDeveloped from sessions of the most recent International Congress on Membranes and Membrane Processes, Membrane Gas Separation gives a snapshot of the current situation, and presents both fundamental results and applied achievements.

Table of Contents

Preface
Contributors
Novel Membrane Materials and Transport in Them
Synthesis and Gas Permeability of Hyperbranched and Cross-linked Polyimide Membranes
Introduction
Molecular Designs for Membranes
Synthesis of Hyperbranched Polyimides
Gas Permeation Properties
Concluding Remarks
References
Gas Permeation Parameters and Other Physicochemical Properties of a Polymer of Intrinsic Microporosity (PIM-1)
Introduction
The PIM concept
Gas Adsorption
Gas Permeation
Inverse Gas Chromatography
Positron Annihilation Lifetime Spectroscopy
Conclusions
Acknowledgements
References
Addition-type Polynorbornene with Si(CH 3)3 Side Groups: Detailed Study of Gas Permeation, Free Volume and Thermodynamic Properties
Introduction
Experimental
Results and Discussion
Conclusions
References
Amorphous Glassy Perfl uoropolymer Membranes of Hyfl on AD : Free Volume Distribution by Photochromic Probing and Vapour Transport Properties
Introduction and Scope
Membrane Preparation
Free Volume Analysis
Molecular Dynamics Simulations
Transport Properties
Correlation of Transport and Free Volume
Conclusions
References
Modelling Gas Separation in Porous Membranes
Introduction
Background
Surface Diffusion
Knudsen Diffusion
Membranes: Porous Structures?
Transition State Theory (TST)
Transport Models for Ordered Pore Networks
Pore Size, Shape and Composition
The New Model
Conclusion
List of Symbols
References
Nanocomposite (Mixed Matrix) Membranes
Glassy Per fl uorolymer- Zeolite Hybrid Membranes for Gas Separations
Introduction
Materials and Methods
Results and Discussion
Conclusions
Acknowledgements
References
Vapor Sorption and Diffusion in Mixed Matrices Based on Te fl onĀ® AF 2400
Introduction
Theoretical Background
Experimental
Results and Discussion
Conclusions
Acknowledgements
References
Physical and Gas Transport Properties of Hyperbranched Polyimide - Silica Hybrid Membranes
Introduction
Experimental
Results and Discussion
Conclusions
References
Air Enrichment by Polymeric Magnetic Membranes
Introduction
Formulation of the Problem
Experimental
Results and Discussion
Conclusions
Acknowledgements
List of Symbols
References
Membrane Separation of CO 2 from Gas Streams
Ionic Liquid Membranes for Carbon Dioxide Separation
Introduction
Experimental
Results
Discussion
Conclusions
References
The Effects of Minor Components on the Gas Separation Performance of Polymeric Membranes for Carbon Capture
Introduction
Sorption Theory for Multiple Gas Components
Minor Components
Conclusions
References
Tailoring Polymeric Membrane Based on Segmented Block Copolymers for CO 2 Separation
Introduction
Tailoring Block Copolymers with Superior Performance
Block Copolymers and their Blends with Polyethylene Glycol
Composite Membranes
Conclusions and Future Aspects
CO 2 Permeation with Pebax -based Membranes for Global Warming Reduction
Introduction
Experimental
Results and Discussions
Conclusions
References
Applied Aspects of Membrane Gas Separation
Membrane Engineering: Progress and Potentialities in Gas Separations
Introduction
Materials and Membranes Employed in GS
Membranes Applications in GS
New Metrics for Gas Separation Applications
Evolution of Natural Gas Treatment with Membrane Systems
Introduction
Market for Natural Gas Treatment
Amine Treaters
Contaminants and Membrane Performance
Cellulose Acetate versus Polyimide
Compaction in Gas Separations
Experimental
Laboratory Tests of Cellulose Acetate Membranes
Field Trials of Cellulose Acetate Membranes
Strategies for Reduced Size of Large-scale Membrane Systems
Research Directions
Summary
Acknowledgements
References
The Effect of Sweep Uniformity on Gas Dehydration Module Performance
Introduction
Theory
Results and Discussion
Conclusion
List of Symbols
References
Index
Table of Contents provided by Publisher. All Rights Reserved.

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