Microstructure of Smectite Clays And Engineering Performance

by ;
Edition: 1st
Format: Hardcover
Pub. Date: 2005-12-19
Publisher(s): CRC Press
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Summary

Certain wastes such as nuclear wastes, are so hazardous that their disposal creates a major challenge requiring considerable technical skill and understanding. Their effective isolation in the ground depends on the properties of the surrounding clays. This authoritative book explains the detailed function of clay-based engineered barriers, gives a number of examples of the design and construction of successful sites, and sets out conceptual and theoretical models for the prediction of their performance. It begins by providing a scientific grounding in the relevant aspects of clay science and successively moves onto the practicalities, while retaining the scientific slant. It will be useful for students, and invaluable for research institutes, specialists in environmental protection agencies and consultants in the field of disposal of hazardous waste.

Author Biography

Roland Pusch is currently the Scientific Head and Managing Director of Geodevelopment International AB, Sweden.

Table of Contents

List of figures
ix
List of tables
xix
Preface xxi
Introduction
1(4)
Reference
4(1)
Smectite clays
5(37)
Particles
5(2)
Basic properties of smectite particles
7(12)
Non-expanding clay minerals in smectite clays
19(7)
Rock-forming minerals in smectitic clays
26(1)
Inorganic amorphous matter in smectitic clays
27(1)
Organic material in smectitic clays
28(1)
Origin and occurrence of commercially exploited smectitic clays
29(11)
References
40(2)
Microstructure of natural smectite clay
42(40)
Objective
42(1)
Definitions
42(1)
Microstructural evolution of sediments
43(4)
Soil microstructure, macrostructure and physical integrity
47(19)
Methods for microstructural analysis
66(14)
References
80(2)
Microstructure of artificial clay-based engineered barriers
82(25)
Objective
82(1)
Preparation of smectitic barriers
82(3)
Microstructural evolution of smectitic `buffer'
85(13)
Microstructural evolution of smectitic fills
98(8)
References
106(1)
Clay properties and microstructural constitution
107(41)
Objective
107(1)
Hydraulic conductivity
107(18)
Gas conductivity of artificially prepared smectite clay
125(3)
Ion diffusion
128(2)
Expandability
130(5)
Microbial function
135(1)
Stress/strain behaviour
136(9)
Concluding remarks
145(1)
References
146(2)
Microstructural function of smectite clay in waste isolation
148(60)
General
148(1)
Clay for isolation of waste landfills
149(31)
Clay for isolation of highly radioactive waste -- deep geological disposal
180(26)
References
206(2)
Long-term function of smectite clay for waste isolation
208(42)
General
208(1)
Clay liners of waste landfills
209(10)
HLW isolation -- a type of temperature-related mineral conversion
219(28)
References
247(3)
Theoretical modelling of the performance of smectite clay microstructure
250(67)
Introduction
250(1)
Purpose and objectives of models
251(1)
Elements of the THMCB problem
252(1)
Basis for modelling
253(15)
Modelling of microstructural evolution
268(1)
Integrated THMC modelling
269(23)
Applicability of models
292(2)
Application of the codes to the AEspoe case
294(14)
Models for special purposes
308(6)
References
314(3)
Index 317

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