Molecular Symmetry and Group Theory : A Programmed Introduction to Chemical Applications, 2nd Edition

by
Edition: 2nd
Format: Hardcover
Pub. Date: 2001-03-01
Publisher(s): WILEY
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Summary

This substantially revised and expanded new edition of the bestselling textbook, addresses the difficulties that can arise with the mathematics that underpins the study of symmetry, and acknowledges that group theory can be a complex concept for students to grasp. Written in a clear, concise manner, the author introduces a series of programmes that help students learn at their own pace and enable to them understand the subject fully. Readers are taken through a series of carefully constructed exercises, designed to simplify the mathematics and give them a full understanding of how this relates to the chemistry. This second edition contains a new chapter on the projection operator method. This is used to calculate the form of the normal modes of vibration of a molecule and the normalised wave functions of hybrid orbitals or molecular orbitals. The features of this book include: A concise, gentle introduction to symmetry and group theory Takes a programmed learning approach New material on projection operators, and the calcultaion of normal modes of vibration and normalised wave functions of orbitals This book is suitable for all students of chemistry taking a first course in symmetry and group theory.

Table of Contents

Preface to the Second Edition vii
How to use the Programmes ix
Symmetry Elements and Operations
1(21)
Objectives
1(1)
Programme text
2(15)
Test
17(4)
Revision notes
21(1)
Point Groups
22(24)
Objectives
22(1)
Programme text
23(19)
Test
42(2)
Revision notes
44(1)
Systematic classification of molecules into point groups
45(1)
Non-degenerate Representations
46(19)
Objectives
46(1)
Programme text
47(15)
Test
62(2)
Revision notes
64(1)
Matrices
65(20)
Objectives
65(1)
Programme text
66(14)
Test
80(4)
Revision notes
84(1)
Degenerate Representations
85(17)
Objective
85(1)
Programme text
86(13)
Test
99(2)
Revision notes
101(1)
Applications to Chemical Bonding
102(20)
Objectives
102(1)
Programme text
103(15)
Test
118(3)
Revision notes
121(1)
Applications to Molecular Vibration
122(17)
Objectives
122(1)
Programme text
123(13)
Test
136(2)
Revision notes
138(1)
Linear Combinations
139(34)
Objectives
139(1)
Programme text
140(25)
Test
165(7)
Revision notes
172(1)
Bibliography 173(1)
Mathematical Data for use with Character Tables 174(2)
Character Tables for Chemically Important Symmetry Groups 176(10)
Index 186

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