New Aspects of Spillover Effect in Catalysis: For Development of Highly Active Catalysts : Proceedings of the Third International Conference on Spill

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Format: Hardcover
Pub. Date: 1993-07-01
Publisher(s): Elsevier Science Ltd
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Table of Contents

Preface
The control of selectivity and stability of catalysts by spillover processesp. 1
Catalyst design based on spillover theoryp. 9
Spillover effect as the key concept for realizing rapid catalytic reactionsp. 17
The history and perspectives of spilloverp. 27
Synergism in the catalysis of supported goldp. 45
The effect of spillover hydrogen on coke formation catalyzed by HY zeolite and pillared montmorillonitep. 53
Spectroscopic insight into spilloverp. 61
Molecular hydrogen-originated solid acid catalystsp. 69
Hydrocracking of residual oils with iron supported zeolite containing catalystp. 77
Attempt at the characterization of spillover adsorbed species during catalysisp. 85
Oxygen spillover for the design of industrial oxidation catalystsp. 95
Surface-to-bulk spillover of hydrogen (proton) in the catalysis of solid heteropoly compoundsp. 105
Ion spillover as the orgin of the NEMCA effectp. 111
Reduction of nitrous oxide by electrochemically-generated spillover hydrogenp. 117
Hydrogen spillover on bimetallic supported Pt-Re particlesp. 125
The role of irreversible and reversible spillover hydrogen in reforming reactionsp. 131
New experimental evidence of the long distance hydrogen back spillover (LD-HBS) mechanism in the paraffins aromatization on Zn and Ga ZSM-5 catalystsp. 137
Hydrogen back spillover phenomena in the aromatization of light alkanes over hybrid catalysts. Mechanistic considerationsp. 143
Hydrogen spillover in the conversion of cyclohexane on ZSM-5 zeolitesp. 151
New active sites induced by hydrogen spillover in reduced Pt-Ga/HZSM-5 aromatization catalystsp. 159
Hydroisomerization of n-pentane over hybrid catalysts containing supported hydrogenation catalystp. 165
The role of spillover in the hydrogenation of oxygenates adsorbed on Ni/Al[subscript 2]O[subscript 3]p. 171
Hydrogenation active sites of molybdenum sulfide catalysts enhanced by Ni and Co organometallicsp. 177
Electrical conductivity study of hydrogen spillover on TiO[subscript 2]p. 183
Direct observation of surface mobility with microscopic techniques: photoemission electron- and field electron microscopyp. 189
Selective hydrogen permeation through metal-dispersed porous alumina membranep. 195
Surface migration of oxygen and of hydrogen in supported metal catalystsp. 201
Catalysis and spilloverp. 207
Oxidative conversion of methane on Cu and Ag-Ni electrodes at artificial unsteady-state mode of the SOFC reactor operationp. 213
Spillover of atomic oxygen and reverse spillover of dioxygen species on Pt/CeO[subscript 2] catalystp. 217
Methoxy formation/spillover on Pd/Al[subscript 2]O[subscript 3] studied by [superscript 13]C, [superscript 1]H NMRp. 223
A surface structure model with allowance for spilloverp. 229
A mathematical model for spilloverp. 235
Promoting effect and hydrogen spillover in supported SeRh[subscript 6]-cluster catalystsp. 241
Heterogeneous catalytic ammoximation of cyclohexanone with ammonia and molecular oxygenp. 247
CO chemisorption and CO-TPR in H[subscript 2] stream with Rh/NaY and Rh-Zn/NaY zeolite catalystsp. 253
Plasma-induced chemisorption of nitrogen and hydrogen on alumina-supported platinum catalystsp. 257
Characterization of palladium catalyst supported on zeolitep. 261
Surface treatments of silica support for nickel catalyst: effects on hydrogen adsorption/desorption and ethane hydrogenolysisp. 265
Coadsorption of CO and NO on Co-Rh cluster-derived bimetallic catalysts and NO spillover phenomenonp. 269
IR study of Rh-Sn bimetallic system and spillover of oxygenp. 273
Spillover to form CH[subscript 3]O on PT/Al[subscript 2]P[subscript 3] and Pd/La[subscript 2]O[subscript 3]p. 277
Nature of Bronsted-acid sites in Ag[subscript 3]PW[subscript 12]O[subscript 40] in the presence of hydrogen and reversible interconversion of protons and hydrogenp. 281
A new concept of hydrogen storage: a [actual symbol not reproducible] materialp. 286
Hydrogenation of isobutylene by spiltover hydrogen from Pt/KA-zeolite to NaY-zeolitep. 289
Influence of support modification on hydrogen spillover in ethylene hydrogenation over Pt/Al[subscript 2]O[subscript 3] catalystp. 293
Hydrogenation of sodium fumarate in the solid phase over fine nickel powderp. 297
New active site for CO hydrogenation formed on promoted Rh catalyst by spillover hydrogenp. 301
Spillover effect for the reducing reaction of CO[subscript 2] with CH[subscript 4] over SiO[subscript 2]-supported transition metal catalysts physically mixed with MgOp. 305
Acceleration of dehydrogenation reactions by hydrogen spilloverp. 309
Carbon-supported dehydrogenation catalysts composed of platinum and ruthenium metalsp. 313
Diffusion of oxygen atoms from active sites during the catalytic oxidation of carbon monoxide with oxygen molybdenum trioxidep. 317
Spillover in catalyses over Co-phthalocyanines supported on titaniap. 321
CO oxidation over gold supported on TiO[subscript 2]p. 325
Platinum metals-ceria synergism in autoexhaust catalystp. 329
Hysteresis and self-oscillation in a selective catalytic reduction of nitric oxide by hydrocarbons on aluminap. 333
The effect of electrochemical pumping of oxygen on catalytic behaviour of metal electrodes in methane oxidationp. 337
Possibility of sulfur spillover on hydrodesulfurization catalysts using radioactive 35Sp. 341
New evidence of the promotion of activity and selectivity through hydrogen spill-over activation of biphasic sulfided hydrotreating catalystsp. 345
Interaction between Co species and Mo species in CoO-MoO[subscript 3]/Al[subscript 2]O[subscript 3]p. 349
Hydrogen spillover on ruthenium promoted molybdenum catalysts for hydrodesulfurizationp. 353
Development of hydrodesulfurization catalysts prepared using metal carbonylsp. 357
Transfer hydrocracking of heavy oils with metal-supported carbon catalystp. 361
Enhancing effect of hydrogen sulfide for cracking of n-hexane over alkali and alkaline earth metal zeolitesp. 365
Spillover effect in methane reforming reactions on Ni-based composite catalysts modified with precious metalsp. 369
Behavior of surface oxygen on a Rh/SiO[subscript 2] catalyst in oxidation of methanep. 373
Utilization of oxide ion transfer for oxidative coupling of methane with membrane reactorsp. 377
Highly dispersed cobalt catalysts modified with transition metals and their applications to CO hydrogenationp. 381
Continuous catalysis on oxides in the presence of spillover hydrogenp. 385
Promoting effect of TiO[subscript 2] addition to CuO-ZnO catalyst on methanol synthesis by catalytic hydrogenation of CO[subscript 2]p. 389
Spillover effect on the stabilization of Cu-Zn catalyst for CO[subscript 2] hydrogenation to methanolp. 393
Hydrogenation of CO[subscript 2] over metal supported fine particlesp. 397
Spillover effects of hydrogen on the reduction of CO[subscript 2] over supported metal catalystsp. 401
Synergistic effect of Pd and Mn[subscript 2]O[subscript 3] in combustion reactionsp. 405
Catalytic gasification activity of iron enhanced by spill-over hydrogenp. 409
Catalytic behavior of iron in the gasification of coal with hydrogenp. 413
Liquid-phase hydroxylation of xylene with hydrogen peroxide over zeolite catalystsp. 417
Promoting effects of noble metals on the detection of ammonia by semiconductor gas sensorp. 421
Manganese oxide and niobium oxide catalysts prepared by a proton exchange and elimination methodp. 425
Promoting role of metal additives in modified Pd catalysts for selective hydrodechlorination of CFC-113p. 429
Author Indexp. 433
Table of Contents provided by Blackwell. All Rights Reserved.

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