Nmr Spectroscopy of Polymers in Solution and in the Solid State

by ;
Format: Hardcover
Pub. Date: 2002-11-28
Publisher(s): American Chemical Society
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Summary

NMR Spectroscopy of Polymers in Solution and in the Solid State brings together a variety of papers on both solution and solid state nuclear magnetic resonance (NMR) in one convenient volume. It includes 31 chapters which are divided into the following sections: overview, solid state NMR of polymers, solution NMR of synthetic polymers, solution NMR of biopolymers, combined NMR-separation techniques, and dynamics of polymers in solution. Practicing NMR spectroscopists, students, and other newcomers to the field will benefit from the book's dual coverage.

Table of Contents

Preface xi
Overview
Advances in the NMR Spectroscopy of Polymers: An Overview
3(19)
H.N. Cheng
Alan D. English
Solid-State NMR of Polymers
Solution and Solid-State NMR Characterization of Ethylene Oxide-Propylene Oxide Composites for Ultra-Low Dielectric Constant Applications
22(10)
Peter A. Mirau
Shu Yang
High-Temperature Solid-State NMR of Cross-Linked, Insoluble, and Unswellable Polymers
32(11)
Khalid Thakur
NMR Studies of the Dynamics of Homo- and Block-Copolymer Poly(ε-caprolactone) Chains in Their Inclusion Compounds with α- and γ-CDs
43(15)
J. Lu
P. A. Mirau
S. Nojima
A. E. Tonelli
Structural Aspects of Low-Molecular-Weight Azocellulose Polymers: A Solid-State 13C NMR Study
58(13)
Suizhou Yang
Monsey M. Jacob
Lian Li
Ashok L. Cholli
Jayant Kumar
Structure of Bombyx mori Silk Fibroin before Spinning in Silkworm
71(12)
Tetsuo Asakura
Jun Ashida
Tsutomu Yamane
Estimation of Physical Properties of Archeological Silk with NMR Relaxation Time and Fluctuation-Dissipation Theorem
83(11)
Riichiro Chujo
Kyoko Fukutani
Yoshiko Magoshi
Solution NMR of Synthetic Polymers: Multidimensional NMR Techniques
Polymer Characterization by 3D Solution NMR
94(29)
Peter L. Rinaldi
Triple Resonance 1H/13C/19F Multidimensional Solution NMR of Fluoropolymers: Experimental Aspects
123(14)
Olivier Assemat
Peter L. Rinaldi
1H/13C/29Si Triple Resonance 3D NMR Study of Poly(dimethylsiloxane) MD3MH
137(10)
Minghui Chai
Peter L. Rinaldi
Sanlin Hu
Multidimensional NMR Studies on Polyurethane-Based Dendritic Wedges
147(19)
Minghui Chai
Peter L. Rinaldi
Uraiwan Puapaiboon
Richard T. Taylor
Compositional and Configurational Assignments of Acrylonitrile Copolymers by 2D NMR Spectroscopy
166(8)
A. S. Brar
Structure Determination of Poly(vinyl alcohol) by 2D NMR Spectroscopy
174(5)
A. S. Brar
R. Kumar
A. Yadav
M. Kaur
2D NMR of Polymers: Comparison of Some of the Standard Pulse Sequences
179(13)
Richard A. Newmark
John L. Battiste
Michael N. Koivula
Solution NMR of Synthetic Polymers: Polymer Solution Studies
Recent Advances in the NMR Description of Polypropylene
192(16)
V. Busico
L. Mannina
A. L. Segre
V. Van Axel Castelli
Effect of Internal Donors in Propylene Polymerization Analyzed with NMR and the Internet
208(8)
Kenichi Shimozawa
Masayoshi Saito
Riichiro Chujo
Branching Polyester Oligomers and Fractals
216(12)
Gavin P. Andrews
Allan H. Fawcett
Majid I. M. Hania
An NMR Study on the Bulk Cationic Copolymerization of Trioxane with 1,3-Dioxepane
228(14)
Min-Hui Cui
Yuli Zhang
Mark Werner
Nan-Loh Yang
Steven P. Fenelli
John A. Grates
1H and 13C Solution NMR of Polyimides Based on 4,4'-Diaminotriphenylmethane: Conformational Analysis Using NOE and Molecular Modeling
242(16)
Antonio Martinez-Richa
Ricardo Vera-Graziano
Dmitri Likhatchev
In-Situ NMR Spectroscopy to Understand the Mechanism of Enzymatic Polymerization of Engineering Polymeric Materials: Poly(phenols)
258(14)
Sangrama K. Sahoo
Wei Liu
Lynne Samuelson
Jayant Kumar
Ashok L. Cholli
Solution NMR of Biopolymers
Origins of Flexibility in Complex Polysaccharides
272(17)
C. Allen Bush
Keratan Sulfates: Structural Investigations Using NMR Spectroscopy
289(9)
Thomas N. Huckerby
Gavin M. Brown
Robert M. Lauder
Ian A. Nieduszynski
Gelling Mechanisms of Glucomannan Polysaccharides and Their Interactions with Proteins
298(8)
I. C. Baianu
E. M. Ozu
Synthesis, Physical, and NMR Characteristics of Di- and Tri-Substituted Cellulose Ethers
306(19)
Navzer (Nozar) D. Sachinvala
David L. Winsor
Walter P. Niemczura
Karol Maskos
Tyrone L. Vigo
Noelie R. Bertoniere
2D NMR Analysis of Ethylcellulose
325(13)
Qiuwei Xu
Mark Brickhouse
Huiming Wang
Combined NMR and Separation Techniques
On-Line HPLC-NMR of Polymers
338(6)
Wolf Hiller
Harald Pasch
Complex Polymer Mixture Analysis by On-Line LC(GPC)-NMR
344(14)
Jian Wu
Kebede Beshah
Copolymer Characterization by SEC-NMR and SEC-MALDI
358(24)
Maurizio S. Montaudo
Coupled SEC-NMR Analysis of Alginates
382(16)
Thomas G. Neiss
H. N. Cheng
Dynamics of Polymers in Solution
Local Segmental Dynamics of Polyacrylates in Concentrated Chloroform Solutions
398(11)
Frank D. Blum
Raj B. Durairaj
NMR Spectroscopic Study of Ion-Conducting 15N-Labeled Polyphosphazenes
409(16)
Thomas A. Luther
Mason K. Harrup
Frederick F. Stewart
Indexes
Author Index
423(2)
Subject Index
425

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