Self-Assembly in Supramolecular Systems

by ;
Format: Hardcover
Pub. Date: 2000-10-01
Publisher(s): Royal Society of Chemistry
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Summary

Molecular self-assembly is a widespread phenomenon in both chemistry and biochemistry. Yet it was not until the rise of supramolecular chemistry that attention has increasingly been given to the designed self-assembly of a variety of synthetic molecules and ions. To a large extent, success in this area has reflected knowledge gained from nature. However, an increased awareness of the latent steric and electronic information implanted in individual molecular components has also contributed to this success. Whilst not yet approaching the sophistication of biological assemblies, synthetic systems of increasing subtlety and considerable aesthetic appeal have been created. Self-assembly in Supramolecular Systems surveys highlights of the progress made in the creation of discrete synthetic assemblies and provides a foundation for new workers in the area, as well as background reading for experienced supramolecular chemists.

Author Biography

Leonard Lindoy is Professor of Inorganic Chemistry at the University of Sydney. He has had wide experience in Host-Guest and Supramolecular Chemistry. His research has focused on rational receptor design for metalion and small molecule recognition, macrocyclic chemistry and the application of self-assembly processes for the construction of metal-containing supramolecules Ian Atkinson is based at James Cook University in Queensland, where his research interests lie in the application of high performance computing to chemical problems. He has undertaken computational studies across a number of areas that include thermodynamic and chemical aspects of transition metal binding to substrates, self-assembly in supramolecular chemistry and crystal engineering

Table of Contents

Self-assembly: What Does it Mean?
1(6)
Introduction
1(2)
Self-assembly
3(2)
Molecular Recognition
5(1)
Scope of the Present Treatment
6(1)
Intermolecular Interactions: The Glue of Supramolecular Chemistry
7(12)
Introduction
7(1)
Ionic and Molecular Recognition
7(1)
The Basics
8(1)
Electrostatic Interactions
9(1)
Hydrogen Bonds
9(4)
Van der Waals Interactions
13(1)
π-π Interactions
13(4)
Charge-transfer Interactions
17(1)
Hydrophobic Binding
17(1)
Final Comments
18(1)
Hydrogen-bonded and π-Stacked Systems
19(28)
Introduction
19(1)
Simple Hydrogen-bonded and/or S-Stacked Assemblies
20(11)
Simple Host-Guest Assemblies
20(6)
Molecular Assembly as a Reaction Template
26(1)
Larger Linked Systems
26(4)
Molecular Tweezers
30(1)
Cyclic Assemblies
31(5)
Some Cyclic Oligomers
32(1)
Molecular Boxes
33(3)
Cylindrical Assemblies
36(1)
Spherical Assemblies
37(7)
Self-assembled Cages
37(7)
Self-replicating Systems
44(2)
Further Supramolecular Categories
46(1)
Rotaxanes
47(40)
Introduction
47(1)
Directed Template Synthesis - Simple Host-Guest Adducts
48(5)
Pseudorotaxanes
53(5)
Simple Charged Rotaxanes
58(6)
Synthesis by Slippage
64(3)
Towards `Switchable' Systems
67(6)
Use of Dialkylammonium Groups for Threading Crowns
73(4)
Uncharged Amide-containing Rotaxanes
77(2)
Cyclodextrin-based Systems
79(8)
Catenanes
87(32)
Introduction
87(1)
Statistical Threading
87(1)
Charged Catenanes
88(19)
Bis-[2]-catenanes
97(4)
Higher-order Catenanes
101(6)
Porphyrin-containing Catenanes
107(2)
Neutral Catenanes
109(4)
Cyclodextrin-containing Systems
113(1)
DNA-based Systems
114(1)
An Immobilised System
114(2)
Other Catenanes and Knots
116(3)
Metal-directed Synthesis - Rotaxanes, Catenanes, Helicates and Knots
119(66)
Introduction
119(1)
Catenanes and Rotaxanes
120(18)
Synthesis of a [2]-Catenane
120(1)
High-yield Synthesis of a [2]-Catenane
121(2)
Other Catenanes and Rotaxanes
123(6)
Poly-metallorotaxanes Containing Conjugated Rods
129(2)
Further Polynuclear Systems
131(2)
Redox Switching
133(2)
A Hybrid [2]-Catenane
135(3)
Helicates
138(1)
Single-stranded Helicates
138(1)
Double-stranded Helicates
139(29)
Systems Based on Di- and Oligo-bipyridyl Derivatives
139(5)
Systems Based on Directly-linked, Oligo-pyridines
144(12)
Systems Incorporating Segmented Terpyridyl Derivatives
156(1)
Systems Based on Benzimidazole and Related Ligands
157(3)
Helicates Derived from Macrocyclic Ligand Systems
160(1)
Systems Based on Non-transition Metal Templates
161(2)
Controlling the Helicity
163(3)
A Helical System Leading to a Multi-intertwined [2]-Catenane
166(2)
Triple Helicates
168(10)
Transition and Post-transition Metal Systems
168(6)
Gallium and Titanium Systems
174(2)
Lanthanide-containing Systems
176(2)
Molecular Knots
178(7)
A High Yield Trefoil Synthesis
183(2)
Further Metal-containing Systems
185(35)
Introduction
185(1)
Metallocycles - Rings, Squares and Related Species
186(21)
Rings
186(3)
Squares
189(6)
Related Polygonal and Polyhedral Systems
195(4)
A Further Cage-like Structure
199(1)
A Linked Metal-cluster System
200(1)
Catenated Metallocycles
201(2)
Porphyrin-containing Metallocycles
203(3)
Higher Oligonuclear Metallocycles
206(1)
Co-ordination Arrays
207(13)
One-dimensional Systems
207(2)
Two-dimensional Systems
209(6)
Cylindrical System
215(1)
Cages
216(2)
Metal-containing Receptors
218(1)
Metal-linked Dendrimers
219(1)
Subject Index 220

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