
Thermodynamics, Statistical Thermodynamics, &Kinetics
by Engel, Thomas; Reid, Philip-
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Summary
Author Biography
Professor Engel's research interests are in the area of surface chemistry, and he has published more than 80 articles and book chapters in this field. He has received the Surface Chemistry or Colloids Award from the American Chemical Society and a Senior Humboldt Research Award from the Alexander von Humboldt Foundation, which has allowed him to establish collaborations with researchers in Germany. He is currently working together with European manufacturers of catalytic converters to improve their performance for diesel engines.
Philip Reid has taught chemistry at the University of Washington since he joined the chemistry faculty in 1995. Professor Reid received his bachelor's degree from the University of Puget Sound in 1986, and his Ph.D. in chemistry from the University of California at Berkeley in 1992. He performed postdoctoral research at the University of Minnesota, Twin Cities, campus before moving to Washington.
Professor Reid's research interests are in the areas of atmosphere chemistry, condensed-phase reaction dynamics, and nonlinear optical materials. He has published more than 70 articles in these fields. Professor Reid is the recipient of a CAREER award from the National Science Foundation, is a Cottrell Scholar of the Research Corporation, and is a Sloan fellow.
Table of Contents
Fundamental Concepts of Thermodynamics | |
What Is Thermodynamics and Why Is It Useful? | |
Basic Definitions Needed to Describe Thermodynamic Systems | |
Thermometry | |
Equations of State and the Ideal Gas Law | |
A Brief Introduction to Real Gases | |
Heat, Work, Internal Energy, Enthalpy, and The First Law of Thermodynamics | |
The Internal Energy and the First Law of Thermodynamics | |
Work | |
Heat | |
Heat Capacity | |
State Functions and Path Functions | |
Equilibrium, Change, and Reversibility | |
Comparing Work for Reversible and Irreversible Processes | |
Determining and Introducing Enthalpy, a New State Function | |
Calculating q, w, , an? for Processes Involving Ideal Gases | |
The Reversible Adiabatic Expansion and Compression of an Ideal Gas | |
The Importance of State Functions: Internal Energy and Enthalpy | |
The Mathematical Properties of State Functions | |
The Dependence of U on V and T | |
Does the Internal Energy Depend More Strongly on V or T? | |
The Variation of Enthalpy with Temperature at Constant Pressure | |
How Are CP and CV Related? | |
The Variation of Enthalpy with Pressure at Constant Temperature | |
The Joule-Thomson Experiment | |
Liquefying Gases Using an Isenthalpic Expansion | |
Thermochemistry | |
Energy Stored in Chemical Bonds Is Released or Taken Up in Chemical Reactions | |
Internal Energy and Enthalpy Changes Associated with Chemical Reactions | |
Hess's Law Is Based on Enthalpy Being a State Function | |
The Temperature Dependence of Reaction Enthalpies | |
The Experimental Determination o? and for Chemical Reactions | |
Differential Scanning Calorimetry | |
Entropy and The Second and Third Laws of Thermodynamics | |
The Universe Has a Natural Direction of Change | |
Heat Engines and the Second Law of Thermodynamics | |
Introducing Entropy | |
Calculating Changes in Entropy | |
Using Entropy to Calculate the Natural Direction of a Process in an Isolated System | |
The Clausius Inequality | |
The Change of Entropy in the Surroundings and = + | |
Absolute Entropies and the Third Law of Thermodynamics | |
Standard States in Entropy Calculations | |
Entropy Changes in Chemical Reactions | |
Refrigerators, Heat Pumps, and Real Engines | |
(Supplemental) Using the Fact that S Is a State Function to Determine the Dependence of S on V and T | |
(Supplemental) The Dependence of S on T and P | |
(Supplemental) The Thermodynamic Temperature Scale | |
Chemical Equilibrium | |
The Gibbs Energy and the Helmholtz Energy | |
The Differential Forms of U, H, A, and G | |
The Dependence of the Gibbs and Helmholtz Energies on P, V, and T | |
The Gibbs Energy of a Reaction Mixture | |
The Gibbs Energy of a Gas in a Mixture | |
Calculating the Gibbs Energy of Mixing for Ideal Gases | |
Expressing | |
Table of Contents provided by Publisher. All Rights Reserved. |
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